首页
最新动态 交流合作 科研项目 论文著作 精彩瞬间 招生招聘
  • Molecular-Weight Dependence of Nucleation Effect of a Liquid Crystalline Polyester β-Nucleating Agent for Isotactic Polypropylene
  • 来源:李锦春教授个人网站 2021-01-25
  • Unlike low-molecular-weight inorganic or organic nucleating agents (NAs), the physical properties, including phase transition and rheological behaviors, of polymeric NAs are greatly influenced by molecular weight. In this paper, the molecular-weight dependence of the β-nucleation behaviors of a polymeric NA (a main-chain liquid crystalline (LC) polyester, PBDPS) was studied in detail. The nucleation effect of PBDPS on isotactic polypropylene (iPP) shows a strong molecular-weight dependence. Lowmolecular-weight PBDPS tended to induce the formation of α-iPP, whereas high-molecular-weight PBDPS tended to induce β-iPP. Moreover, the relative content of β-iPP crystals (kβ) first increased and then decreased as the molecular weight of PBDPS increased, with the maximum value (86.1%) obtained when 2 wt % PBDPS21.2k was incorporated. Furthermore, the stiffness, toughness, and heat distortion temperature (HDT) of iPP were simultaneously improved by incorporating PBDPS.
  • [来源:中国聚合物网]
  • 了解更多请进入: 李锦春教授个人网站
相关新闻
  • · Nonisothermal Crystallization, Melting Behaviors, and Mechanical Properties of Isotactic Polypropylene Nucleated with a Liquid Crystalline Polymer
  • · 液晶聚合物β成核剂/等规聚丙烯的等温结晶动力学和熔融行为
  • · Preparation of Liquid Crystalline Polymer Networks Containing a Cinnamyl Group in the Main Chain with Tunable Thermal Actuation Behavior
  • · Fire retardance and smoke suppression of polypropylene with a macromolecular intumescent flame retardant containing caged bicyclic phosphate and piperazine

关于我们  |  联系我们  

网站:中国聚合物网

polymer.cn Copyright ©2017