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Synthesis of Monodisperse Hollow Polymer Microspheres with Functional Groups by Distillation Precipitation Polymerization
Monodisperse hollow polymer microspheres having various functional groups on the shell-layer, such as carboxylic acid, pyridyl and amide, were prepared by two-stage distillation precipitation polymerization in neat acetonitrile in the absence of any stabilizer or additive, during which monodisperse poly(methacrylic acid) (PMAA) afforded from the
first-stage polymerization was utilized as the seeds...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6591.html |
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Preparation of Narrow or Monodisperse Polymer Microspheres by Distillation-precipitation Polymerization
Narrow- or monodisperse poly(divinylbenzene-co-acrylonitrile) (poly(DVB-co-AN))
microspheres with reactive cyano group were prepared by distillation-precipitation
polymerization of divinylbenzene (DVB) and acrylonitrile (AN) in neat acetonitrile
with 2,2′-azobis(isobutyronitrile) (AIBN) as initiator in the absence of any stabilizer
or additive without stirring. The effects of the comonomer feed o...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6582.html |
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Synthesis of Monodisperse Titania/Polymer Core-shell Hybrid Microspheres
Monodisperse titania/polymer core-shell microspheres were prepared by a two-stage reaction with titania as core and poly(ethyleneglycol dimethacrylate) (PEGDMA)
as shell, in which the titania cores were synthesized by a sol-gel method and subsequently grafted with 3-trimethoxysilyl methacrylate as the first-stage reaction to incorporate the vinyl groups on the surface of inorganic core. The PEGDMA...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6572.html |
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Synthesis of Hollow Fluorescent Polymer Microspheres with Movable Magnetic Cores
Low-dispersity hollow poly[(ethyleneglycol dimethacrylate)-co-(N-vinylcarbazole)] (P(EGDMA-co-NVCz)) fluorescent microspheres with movable magnetic cores were prepared by quantitative removal of the silica component in hydrofluoric acid aqueous solution from the corresponding magnetite/silica/P(EGDMA-co-NVCz) tri-layer hybrid microspheres. The tri-layer microspheres with magnetic cores and fluores...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6566.html |
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Preparation of Monodisperse Hydrophilic Polymer Microspheres with N,N?-Methylenebisacrylamide as Crosslinker by Distillation Precipitation Polymerization
Highly crosslinked cauliflower-like poly(N,N-methylenebisacrylamide) particles were prepared by distillation precipitation polymerization in neat acetonitrile with 2,2-azobisisobutyronitrile as initiator. Monodisperse hydrophilic polymer microspheres with various functional groups, such as amide, pyrrolidone and carboxylic acid, with a spherical shape and smooth surface in the size range 120–60...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6565.html |
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Synthesis of pH-sensitive Hollow Polymer Microspheres and Their Application as Drug Carriers
The pH-sensitive hollow poly(N,N0-methylene bisacrylamide-co-methacrylic acid) (P(MBAAm-co-MAA)) microspheres were prepared by a two-stage distillation precipitation polymerization to afford a core–shell poly(methacrylic acid)/poly(N,N0-methylene bisacrylamide-co-methacrylic acid) (PMAA/(P(MBAAm-co-MAA))) microsphere with subsequent removal of poly(methacrylic acid) (PMAA) core. PMAA/P(MBAAm-co-M...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6535.html |
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Synthesis of pH-sensitive Polymer Hollow Microspheres with Movable Magnetic Core
The pH-sensitive hollow poly(N,N0-methylenebisacrylamide-co-methacrylic acid) (P(MBAAm-co-MAA)) microspheres with movable magnetic/silica (Fe3O4/SiO2) cores were prepared by the selective removal of poly(methacrylic acid) (PMAA) layer in ethanol/water from the corresponding Fe3O4/SiO2/PMAA/P(MBAAm-co-MAA) tetra-layer microspheres, which were synthesized by the distillation precipitation copolymeri...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6534.html |
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Monodisperse Temperature-responsive Hollow Polymer Microspheres: Synthesis, Characterization and Application
Temperature-responsive hollow poly(N-isopropylacrylamide) (PNIPAAm) microspheres were prepared by a two-stage distillation precipitation polymerization to afford a core–shell microspheres with subsequent removal of poly(methacrylic acid) (PMAA) core. PMAA@PNIPAAm core–shell microspheres were synthesized by the second-stage polymerization of NIPAAm in the presence of PMAA as core with N,N0-
methy...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6530.html |
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Exfoliated Graphite Oxide Decorated by PDMAEMA Chains and Polymer Particles
Exfoliated graphite oxide (GO) sheets with hydroxyl groups and amine groups on the surface were prepared by modification of graphite. Atom transfer radical polymerization (ATRP) initiator molecules were grafted onto the GO sheets by reactions of 2-bromo-2-methylpropionyl bromide with hydroxyl groups and amine groups. Poly-(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) chains on the surface of GO ...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6521.html |
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Polyethyleneimine functionalized polymer microsphere: A novel delivery vector for cells
Monodisperse poly(ethylene glycol dimethacrylate-co-methacrylic acid) (P(EGDMA-co-MAA)) microspheres with two different diameters (69 and 160 nm) were facilely synthesized via distillation precipitation polymerization in neat acetonitrile, and these microspheres interacted with the amino groups of polyethyleneimine (PEI) chains though hydrogen-bonding as well as electrostatic interactions to form ...
http://www.polymer.cn//ss/yangxinlin/publicationsshow_6510.html |
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