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Single-Chain Mechanics of Poly(N,N-diethylacrylamide) and Poly(N-isopropylacrylamide): Comparative Study Reveals the Effect of Hydrogen Bond Donors
关键字:Poly(N,N-diethylacrylamide), Poly(N-isopropylacrylamide)
The
single-chain mechanics of two similar thermosensitive polymers, poly(N,N-diethyl-acrylamide) (PDEAM) and poly(N-isopropyl-acrylamide) (PNIPAM), have been studied by atomic
force microscopy-based single-molecule
force spectroscopy (SMFS). In a typical nonpolar organic
solvent, octane, both the two polymers show the same
inherent elasticity, although they have different substitutional groups. ...
http://www.polymer.cn/research/sy_info19125 |
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SYNTHESIS AND CRYSTALLIZABILITY OF POLY(ETHYLENE GLYCOL) -b-POLY (ε-CAPROLACTONE) -POLY (ETHYLENE GLYCOL)
关键字:PEG-PCL-PEG,triblock polymers, stannous octoate, crystallizability A family of poly (ethylene glycol)-b-poly(ε-caprolactone)-b-poly (ethylene glycol) has been prepared in high yields by a two step method. Their thermal and crystallization behaviors were studied by DSC and WXRD. The results illustrated&nbs...
http://www.polymer.cn/research/dis_info13897 |
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PREPARATION OF UV-CROSSLINKED BIODEGRADABLE POLY(p-DIOXANONE) / POLY (ETHYLENE GLYCOL) FILMS
关键字: poly(p-dioxanone), polyethylene glycol, UV-initiated polymerization, crosslinked film Poly (p-dioxanone) / Poly (ethylene glycol) (PPDO / PEG) crosslinked films were prepared through the UV-initiated polymerization of acrylated PPDO with PEG200 diacrylate. The acrylated PPDO was prepared from the reaction of acryloyl ch...
http://www.polymer.cn/research/dis_info13161 |
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Effect of ionic interaction on the miscibility and crystallization behavior of poly(ethylene glycol)/poly(L-lactic acid) blends
关键字:Poly(ethylene glycol); Poly(L-lactic acid); Miscibility; Crystallization The effects of end groups (-NH2) of poly(ethylene glycol) (PEG) on the miscibility and crystallization behaviors of binary crystalline blends of PEG/poly(L-lactic acid) (PLLA) were investigated by differential scanning calorimetry (DSC) and ...
http://www.polymer.cn/research/dis_info5279 |
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THE PREPARATION AND CHARACTERIZATION OF POLY(ETHYLENEGLYCOL)/POLY(LACTIC ACID) MULTIBLOCK COPOLYMERS
关键字:Poly(ethylene glycol);poly(lactic acid);PELA;block copolymers Poly(ethylene glycol)/poly(lactic acid) multiblock copolymers (PELA) with varying composition were prepared through successive polymerization of PEG and lactic acid synthesized by a coupling reaction, and high molecular weight PELA were obtained.&nbs...
http://www.polymer.cn/research/dis_info3352 |
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POLY(N-ISOPROPYLACRYLAMIDE) MICROGELS WITH SHORT CHAIN POLY(VINYLAMINE) GRAFTS: PREPARATION AND CHARACTERIZATION
关键字:POLY,ISOPROPYLACRYLAMIDE,MICROGELS,WITH,SHORT,CHAIN,POLY,VINYLAMINE,GRAFTS,PREPARATION,AND,CHARACTERIZATION, Poly(N-isopropylacrylamide) (PNIPAM) microgel is known to be thermosensitive, exhibiting a phase transition behavior in aqueous solution at about 32 oC. These microgels are swollen at room temperature and shrunk as the temperature is i...
http://www.polymer.cn/research/dis_info3205 |
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The preparation of Poly(L-lactic acid)- Poly(ethylene adipate)ester Multiblock Copolymers
关键字:Poly(L-lactic acid), Poly(ethylene adipate), Multiblock copolymer The multiblock copolymers derived from poly(L-lactic acid) (PLLA) and Poly(ethylene adipate)ester (PEA) were prepared with the coupling reaction between PLLA and PEA oligomers with -NCO terminals. Fourier transform infrared (FTIR) was used ...
http://www.polymer.cn/research/dis_info1665 |
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Super tough biobased poly(ethylene 2,5-furandicarboxylate) materials: synthesis and thermo-mechanical properties of poly(ethylene 2,5-furandicarboxylate-mb-poly(tetramethylene glycol)) multiblock copolymers.
Poly(ethylene 2,5-furandicarboxylate) (PEF) is a biobased polyester with superior thermo-mechanical and gas barrier properties than poly(ethylene terephthalate) (PET), the most widely used petroleum-based polyester. However, PEF is more brittle than PET. To toughen PEF, a series of P(EF-mb-PTMG) (PETF) multiblock copolymers with high intrinsic viscosity were successfully synthesized via melt pol...
http://www.polymer.cn//ss/wulinbo/publicationsshow_14060.html |
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[Macromol. Chem. Phys.] Multiresponsive Properties of Triple-Shell Architectures with Poly( N , N -diethylaminoethyl methacrylate), Poly( N -vinylcaprolactam), and Poly( N , N -dimethylaminoethyl methacrylate) as Building Blocks
Triple-shell architectures, consisting of poly[( N,N -diethylaminoethyl methacrylate)- block -( N-vinylcaprolactam)- block -( N,N -dimethylaminoethyl methacrylate)] triblock copolymers, are obtained by sequential reversible addition–fragmentation chain transfer polymerizations, using a terminal-modifi ed hyperbranched poly( β -cyclodextrin) core as a macro chain transfer agent. ...
http://www.polymer.cn//ss/tianwei/publicationsshow_7914.html |
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In vitro degradation of biodegradable blending materials based on poly(p-dioxanone) and poly(vinyl alcohol)-graft-poly(p-dioxanone) with high molecular weights
Amphiphilic biodegradable graft copolymer, poly(vinyl alcohol)-graft-poly(p-dioxanone) (PVA-g-PPDO), was used to prepare a new biodegradable material by blending with poly(p-dioxanone) (PPDO). The in vitro degradation properties of the copolymer and blends with different contents of PVA-g-PPDO were studied in phosphate buffer at 37 degrees C. The degradation processes of the PVA-g-PPDO and its ble...
http://www.polymer.cn//ss/wugang/publicationsshow_7827.html |
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