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Synthesis
of
Macroporous Polymer through Heterogeneous Polymerization by Redox Initiator and
Application
as Scaffold for Pd Nanoparticles
Heterogeneous polymerization
of
the binary hydrophilic/hydrophobic monomers initiated by the redox pair to synthesize macroporous amphiphilic copolymers is reported. This strategy employs the initiator
of
the hydrophilic/hydrophobic redox pair
of
K2S2O8/1-octylamine or the hydrophilic/hydrophilic redox pairs
of
K2S2O8/diethylamine and K2S2O8/Na2SO3 to initiate the polymerization on the O/W emulsio...
http://www.polymer.cnt//ss/zhangwangqing/publicationsshow_4275.html
Surface modification
of
potassium titanate whisker and its application to thermal insulation coil coatings
Potassium titanate whiskers (PTW) were modified by silane coupling agent KH-570 before and after coating with inorganic SiO2. The influence
of
the PTWs modified by silane coupling agent before and after coating with SiO2 on thermal insulation performance
of
coil coating were compared. PTWs before and after modification were characterized by infrared (IR) spectroscopy and thermo-gravimetry (TG). Th...
http://www.polymer.cnt//ss/caizhiqi/publicationsshow_4188.html
Synthesis
of
efficient and reusable palladium catalyst supported on pH-responsive colloid and its application to Suzuki and Heck reactions in water
www.sciencedirect.com/science/article/pii/S002195170700262X An efficient and reusable pH-responsive colloid supported palladium catalyst was synthesized by loading 3-nm Pd nanoparticles into the pH-responsive colloid
of
core–shell microspheres
of
poly[styrene-co-2-(acetoacetoxy)ethyl methacrylate-co-methyl acrylic acid] (PS-co-PAEMA-co-PMAA). The colloidal scaffold
of
the core–shell m...
http://www.polymer.cnt//ss/zhangwangqing/publicationsshow_4039.html
Synthesis
of
gold nanoparticles stabilized with poly(N-isopropylacrylamide)-co-poly(4-vinyl pyridine) colloid and their application in responsive catalysis
www.sciencedirect.com/science/article/pii/S1381116907005870 The copolymer
of
poly(N-isopropylacrylamide)-co-poly(4-vinylpyridine) was synthesized by free radical copolymerization
of
4-vinylpyridine and N-isopropylacrylamide. The copolymer synthesized with the feed monomer ratio
of
4-vinylpyridine/N-isopropylacrylamide equal to 1/3 was associated to form thermoresponsive colloid in neutral water a...
http://www.polymer.cnt//ss/zhangwangqing/publicationsshow_4036.html
Synthesis
of
noble metal nanoparticles embedded in the shell layer
of
core-shell poly(styrene-co-4-vinylpyridine) micospheres and their application in catalysis
pubs.acs.org/doi/abs/10.1021/cm703378c The noble metal nanoparticles
of
Pd, Au, and Ag embedded in the shell layer
of
core−shell poly(styrene-co-4-vinylpyridine) micospheres were synthesized, and the catalytic activity
of
the shell-embedded Pd nanoparticles was investigated. To increase the accessible active site and therefore increase the catalytic activity
of
noble metal nanoparticles, th...
http://www.polymer.cnt//ss/zhangwangqing/publicationsshow_4034.html
One-Stage Synthesis
of
Cagelike Porous Polymeric Microspheres and
Application
as Catalyst Scaffold
of
Pd Nanoparticles
pubs.acs.org/doi/abs/10.1021/ma200320a One-stage synthesis
of
cagelike porous polymeric microspheres and their application as catalyst scaffold
of
Pd nanoparticles are discussed. The synthesis
of
cagelike porous polymeric microspheres is achieved by W/O/W emulsion polymerization
of
a surfactant monomer
of
N-(4-vinylbenzyl)-N,N-dibutylamine hydrochloride and a hydrophobic monomer
of
styrene in wat...
http://www.polymer.cnt//ss/zhangwangqing/publicationsshow_4018.html
Fabrication
of
quantum dots-encoded microbeads with a simple capillary fluidic device and their application for biomolecule detection
Monodispersed quantum dots (QDs)-encoded polymer microbeads were generated using a simple capillary fluidic device (CFD). The polymer and QDs solution was emulsified into monodispersed microdroplets by the CFD and obtained droplets were solidified via solvent evaporation. Polymer microbeads can be fabricated in a range
of
different sizes through changing the flow rates
of
the two immiscible phases...
http://www.polymer.cnt//ss/zhangpengfei/publicationsshow_3912.html
Preparation
of
poly(p-styrenesulfonic acid) grafted multi-walled carbon nanotubes and their application as a solid-acid catalyst
Poly(p-styenesulfonate acid)-grafted multi-walled carbon nanotubes (PSSA-g-MWCNTs) were prepared by in situ polymerization
of
sodium p-styrenesulfonate in the presence
of
MWCNTs, followed by refluxing with concentrated hydrochloric acid. In this reaction system, sodium p-styrenesulfonate served not only as the reaction monomer but also as an amphiphilic dispersant to disperse pristine MWCNTs in wa...
http://www.polymer.cnt//ss/yangdongfd/publicationsshow_3591.html
Surface Modification
of
Hydrophobic PMMA Intraocular Lens by the Immobilization
of
Hydroxyethyl Methacrylate for Improving
Application
in Ophthalmology
To improve application
of
hydrophobic polymethyl methacrylate intraocular lens (PMMA IOL) in a convenient and continuous way, 2-hydroxyethyl methacrylate (HEMA) was immobilized by dielectric barrier discharge plasma at relatively high pressure. The hydrophilicity and topography
of
the modified IOL surface were comprehensively evaluated by contact angle and atomic force microscopy, while the surf...
http://www.polymer.cnt//ss/leslieliu/publicationsshow_3586.html
Water-Soluble Starlike Poly(acrylic acid) Graft Polymer: Preparation and
Application
as Templates for Silver Nanoclusters
Water-soluble starlike polymers containing concentrated carboxyl groups were conveniently synthesized via the combination
of
“click” chemistry and atom transfer radical polymerization (ATRP). The starlike polymer was composed
of
a shorter polyacrylate main chain and longer poly(acrylic acid) side chains. Alkyne and azide groups were introduced to the structure units
of
the main chain b...
http://www.polymer.cnt//ss/yumm/publicationsshow_3487.html
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