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Synthesis of Functional Comb-block-Comb Copolymers Based on RAFT and Click Chemistry and their Self-assembly
The preparation of comb block comb (CBC) copolymers are based on three-step synthetic strategies as shown in Scheme 1: (1) the synthesis of pyrenyl-Br, pyrenyl-N3 and macromolecular CTA (macro-CTA) poly (poly (ethylene glycol) methacry...
http://www.polymer.cn/research/dis_info7507 |
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PROTEIN ADSORPTION ON POLYMER SURFACE WITH CONTROLLED TOPOGRAPHY AND CHEMISTRY
关键字:PROTEIN,ADSORPTION,POLYMER,SURFACE,WITH,CONTROLLED,TOPOGRAPHY,AND,CHEMISTRY, It is believe that the initial rapid adsorption of plasma proteins at the blood-materials interface plays an important role in the subsequent events and that the structures, orientations and conformations of the proteins layer det...
http://www.polymer.cn/research/dis_info1533 |
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CHEMISTRY OF [O-NX] TITANIUM (IV) COMPLEXES FOR OLEFIN POLYMERIZATION
关键字:CHEMISTRY,TITANIUM,COMPLEXES,FOR,OLEFIN,POLYMERIZATION, The discovery of new olefin polymerization catalysts is of great fundamental scientific and technological importance. In our study on catalysis
http://www.polymer.cn/research/dis_info1506 |
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Novel perfluorocyclobutyl (PFCB)-containing polymers formed by click chemistry
关键字:Poly(alkyl aryl) ethers, Perfluorocyclobutane (PFCB), Click chemistry
The synthesis and characterization of a novel class of linear poly(alkyl aryl) ethers containing 1,2,3-triazolyl and perfluorocyclobutyl units have been described. These polymers were readily prepared from the Huisgen’s 1,3-dipolar cycloaddition of poly(ethylene glycol) diazides and 1,2-bis(4-ethynylphenoxy)perfluorocyclobutane that is defined as ‘click chemistry’ recently....
http://www.polymer.cn/research/sy_info18194 |
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Journal of Polymer Science Part A: Polymer Chemistry 2011, 49, 5293
关键字:copolymerization, reactivity ratios, chain sequence, crystallization A series of copolymers containing ε-caprolactone (CL) and 4-methyl-ε-cap-rolactone (MeCL) were synthesized by ring-opening polymerization (ROP) using Tin(Ⅱ)bis(2-ethylhexanoate)(Sn(Oct)2) or Novozym 435 as catalyst. The molecular structure and weight of copolymers were determined by Nuclear Magnetic Resonance (NMR) and size exclusion chromatography (SEC), respectively. Our kinetic...
http://www.polymer.cn/research/sy_info14699 |
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Journal of Macromolecular Science, Part A: Pure and Applied Chemistry 2012 49, 124
关键字:ATRP /PCL/PDEAEMA /pH sensitivity/ ROP/self-assembly Four-arm star block polymers consisting of hydrophobic poly(ε-caprolactone) (PCL) block and hydrophilic poly(2-(diethylamino) ethyl methacrylate)) (PDEAEMA) block were successfully synthesized by ring opening polymerization (ROP) and atom transfer radical polymerization (ATRP). Chain lengths of PDEAEMA segments were varied to obtain a series of star copolymers with different hydrophilic/hy...
http://www.polymer.cn/research/sy_info14685 |
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Design and synthesis of an end-functionalized polystyrene with 8-hydroxyquinoline zinc complexes via a combination of ATRP, click reaction and coordination chemistry
8-Hydroxyquinoline (8Q) is one of the best green luminescent materials in organic light-emitting diodes (OLEDs) up to now, which can also chelate many metal ions, the corresponding complexes possess high luminescent efficiency and quan...
http://www.polymer.cn/research/dis_info16512 |
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Precision synthesis of shape amphiphiles with diverse surface chemistry, polymer architecture, and chain topology
To reveal the structure-property relationship, it is a prerequisite to synthesize materials with high purity and precise structure, which is nontrivial for macromolecules. In recent years, our group has been focusing on the synthesis&n...
http://www.polymer.cn/research/dis_info16454 |
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Layer-by-Layer Assembled Self-Healing Coatings
关键字:Self-healing, layer-by-layer assembly, superhydrophibicity, polyelectrolyte, surface chemistry Self-healing is an intrinsic property of living organisms. Imparted with self-healing ability, artificial materials can restore their original mechanical stability and function after damage. Recently, considerable effort has been devoted to the&...
http://www.polymer.cn/research/dis_info16333 |
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Ionic Liquids for Cellulose–A Perfect Green Combination?
关键字:Ionic liquids, cellulose chemistry, sustainability Ionic Liquids (IL), which are low melting salts of organic cations and inorganic or organic anions, often are referred to as green solvents. Negligible volatility (vapor pressure) is the main argument for backing this attribute.&n...
http://www.polymer.cn/research/dis_info16025 |
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