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The stability of covalently immobilization of TEMPO on the polymer surface through ionic liquid linkage: a comparative and model research.
Covalently immobilizing the active sites or ligands on a polymer surface is an efficient strategy to achieve a full use of expensive organic parts. In this work, 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) was anchored onto polystyrene beads through an ether bond or an ionic liquid bridge. We quantitatively compared their thermal stabilities at nitrogen atmosphere and their chemical stabilities i...
http://www.polymer.cnt//ss/wangjianli/publicationsshow_8403.html |
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Temperature-sensitive hydrogel modified by polymerizable liquid crystal AAc-Brij-58: optical and protein adsorption/desorption behaviors
To avoid template-like action of polyoxyethylene 20 cetyl ether (Brij-58) in hydrogel matrix, a polymerizable liquid crystal AAc-Brij-58 based acrylic acid (AAc) and Brij-58, and poly(NIPAm-co-AAc-Brij-58) (ACHX) hydrogels based on N-isopropylacrylamide (NIPAm) and AAc-Brij58 were synthesized by esterification and free-radical polymerization. The chemical structures of resulting ACHX hydroge...
http://www.polymer.cnt//ss/tjzqs/publicationsshow_8236.html |
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200. Catalytic liquid marbles: Ag nanowire-based miniature reactors for highly efficient degradation of methylene blue.
Ag nanowire-based catalytic liquid marbles are fabricated as miniature reactors, which demonstrate highly efficient, support-free and rate-controllable heterogeneous degradation of methylene blue, with catalytic efficiency close to 100%. Our miniature catalytic liquid marbles are essential for reactions involving highly toxic/hazardous or costly reactants, where small volume preliminary reactions ...
http://www.polymer.cnt//ss/liutianxi/publicationsshow_7132.html |
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199. Plasmonic Liquid Marbles: A Miniature Substrate-less SERS Platform for Quantitative and Multiplex Ultratrace Molecular Detection.
Inspired by aphids, liquid marbles have been studied extensively and have found application as isolated microreactors, as micropumps, and in sensing. However, current liquid-marble-based sensing methodologies are limited to qualitative colorimetry-based detection. Herein we describe the fabrication of a plasmonic liquid marble as a substrate-less analytical platform which, when coupled with ultras...
http://www.polymer.cnt//ss/liutianxi/publicationsshow_7131.html |
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Liquid acid-catalysed fabrication of nanoporous 1,3,5-triazine frameworks with efficient and selective CO2 uptake
New classes of nanoporous organic polymers based on 1,3,5-triazine units (NOP-1–6) were synthesized via a straightforward, methane-sulfonic acid-catalysed, cost-effective Friedel–Crafts reaction of 2,4,6-trichloro-1,3,5-triazine and tetrahedral building blocks. Among them, NOP-3 with a Brunauer–Emmet–Teller (BET) specific surface area up to 894 m2g?1and the total volume exceeding 0.41 m3g?1exh...
http://www.polymer.cnt//ss/guipengyu/publicationsshow_6698.html |
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Mechanical and Damping Properties of Epoxy/Liquid Rubber Intercalating Organic Montmorillonite Integration Nanocomposites
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http://www.polymer.cnt//ss/zouhuawei/publicationsshow_6468.html |
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Liquid Crystalline Transition and Gel-Sol Transitions for concentrated Microcrystalline Cellulose (MCC)/1-Ethyl-3-Methylimidazolium Acetate (EMIMAc) Solutions
Liquid crystalline (LC) phase transition and gel?sol transition in the solutions of microcrystalline cellulose (MCC) and ionic liquid (1-ethyl-3-methylimidazolium acetate, EMIMAc) have been investigated through a combination of polarized optical microscope (POM) observation and rheological measurements. Molecular LC phase forms at the 10 wt % cellulose concentration, as observed by POM, whereas th...
http://www.polymer.cnt//ss/hongzansong/publicationsshow_6438.html |
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A cocrystal strategy for the precipitation of liquid 2,3-dimethyl pyrazine with hydroxyl substituted benzoic acid and a Hirshfeld surfaces analysis of them
We here report the cocrystal strategy for the precipitation of liquid 2,3-dimethyl pyrazine (2,3-DMP) with the hydroxyl substituted benzoic acids: salicylic acid (SA), m-hydroxybenzoic acid (MHBA) and p-hydroxybenzoic acid (PHBA) under identical conditions, and obtained three cocrystals (cocrystal 1–3), respectively. Their crystal structures were characterized by single-crystal X-ray diffraction,...
http://www.polymer.cnt//ss/sunbw/publicationsshow_6123.html |
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Hemiphasmidic Side-Chain Liquid Crystalline Polymer: From Smectic C Phase to Columnar Phase with a Bundle of Chains as Its Building Block
We synthesized a new hemiphasmidic side-chain liquid crystalline polymer (P-n, n is the number of carbons in alky tail of the side chain, n = 4?12) using free radical polymerization. The side chain of P-n has a biphenyl in the middle, linked to the polystyrene backbone and to the terminal phenyl group with three alkyl tails via only methyleneoxy units. Upon increasing n,...
http://www.polymer.cnt//ss/renxiangkui/publicationsshow_5754.html |
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High tensile strength and high ionic conductivity bionanocomposite ionogels prepared by gelation of cellulose/ionic liquid solutions with nano-silica
Novel bionanocomposite ionogels consisting of an ionic liquid (IL) 1-ethyl-3-methylimidazolium acetate
(EMIMAc), microcrystalline cellulose (MCC) and nano-silica (nano-SiO2) particles with high tensile strength
and high ionic conductivity have been successfully prepared. Dynamic light scattering (DLS) and
transmission electron microscopy (TEM) measurements reveal a homogeneous dispersion of nano-S...
http://www.polymer.cnt//ss/hongzansong/publicationsshow_5494.html |
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