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【36 ACS Sustainable Chemistry & Engineering】 Sustainable conversion of mixed plastics into porous carbon nanosheet with high performances in uptake of carbon dioxide and storage of hydrogen
Conversion of waste plastics into high value-added carbon nanomaterials has gained wide research interest due to the requirement of sustainable development and the ever-increasing generation of waste plastics. However, most of studies are limited to single component plastic; besides, little attention has been paid to carbon nanosheets (CNS). Herein, CNS were prepared by catalytic carbonization of ...
http://www.polymer.cnt//ss/gongjiang_hust/publicationsshow_13247.html |
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A nitrogen-rich, azaindole-based microporous organic network: synergistic effect of local dipole–π and dipole–quadrupole interactions on carbon dioxide uptake
A new type of microporous organic polymer with azaindole units (N-PEINK) has been designed. The resulting N-PEINK exhibits good chemical and thermal stability with a decomposition temperature of 550 °C. Taking advantage of the synergistic effect of local dipole–π and dipole–quadrupole interactions between azaindole and carbon dioxide (CO2), the CO2 uptake capacity of the polymer reaches 20.8...
http://www.polymer.cnt//ss/changguanjun/publicationsshow_9977.html |
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Highly efficient one-pot/one-step synthesis of multiblock copolymers from three-component polymerization of carbon dioxide, epoxide and lactone
It is a long-standing challenge to combine mixed monomers into multiblock copolymer (MBC) in a one-pot/one-step polymerization manner. We report the first example of MBC with biodegradable polycarbonate and polyester blocks that were synthesized from highly efficient one-pot/one-step polymerization of cyclohexene oxide (CHO), CO2 and ε-caprolactone (ε-CL) in the presence of zinc...
http://www.polymer.cnt//ss/xhzhang/publicationsshow_8489.html |
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Alternating Copolymerization of Carbon Dioxide and Propylene Oxide Under Bifunctional Cobalt Salen Complexes: Role of Lewis Base Substituent Covalent Bonded on Salen Ligand
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http://www.polymer.cnt//ss/BinyuanLiu/publicationsshow_4919.html |
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Formation of Cyclic Carbonates from Carbon Dioxide and Epoxides Coupling Reactions Efficiently Catalyzed by Robust, Recyclable One-component Aluminum-Salen Complexes
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http://www.polymer.cnt//ss/BinyuanLiu/publicationsshow_4914.html |
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167. Polymorphism of electrospun polyvinylidene difluoride/carbon nanotube (CNT) nanocomposites: Synergistic effects of CNT surface chemistry, extensional force and supercritical carbon dioxide treatment.
In this work, the effects of single-walled carbon nanotubes (SWCNT) surface chemistry on the polymorphism behaviors of electrospun poly(vinylidene difluoride) (PVDF) nanofibers collected under high extensional force and subsequently treated with supercritical carbon dioxide (SCCO2) are investigated via X-ray diffraction, infrared and Raman spectroscopy. It is found that the SWCNTs with hydroxyl gr...
http://www.polymer.cnt//ss/liutianxi/publicationsshow_4080.html |
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Rational design of a novel indole-based microporous organic polymer: enhanced carbon dioxide uptake via local dipole–π interactions
关键字：indole-based microporous organic polymer, local dipole–p interactions
An indole-based microporous organic polymer (PINK) has been obtained by the condensation polymerization of 1,3,5-tris-(4-fluorobenzoyl)benzene with 3,30-diindolylmethane via a catalyst-free nucleophilic substitution reaction. Due to the local dipole–p interactions between indole and carbon dioxide (CO2), the uptake capacity for CO2 reaches up to 16.0 wt% (1.0 bar, 273 K), and the high (CO2/N2),...
http://www.polymer.cn/research/sy_info19478 |
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A nitrogen-rich, azaindole-based microporous organic network: synergistic effect of local dipole–π and dipole–quadrupole interactions on carbon dioxide uptake
关键字：microporous organic polymer, dipole–π and dipole–quadrupole interactions
A new type of microporous organic polymer with azaindole units (N-PEINK) has been designed. The resulting N-PEINK exhibits good chemical and thermal stability with a decomposition temperature of 550 °C. Taking advantage of the synergistic effect of local dipole–π and dipole–quadrupole interactions between azaindole and carbon dioxide (CO2), the CO2 uptake capacity of the polymer reaches 20.8...
http://www.polymer.cn/research/sy_info19477 |
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Formation of plasticized polyvinyl butyral-zirconia hybrid films and their application to laminated glass
关键字：plasticized Poly (vinyl butyral); zirconium dioxide; laminated Glass; sol–gel process; thermal/mechanical properties
Poly(vinyl butyral)(PVB) is widely used as the film sandwiched in the laminated glass owing to its merits,such as sturdiness, flexibility and great adhesiveness with glass as well as the high impact strength at low temperature.&nb...
http://www.polymer.cn/research/dis_info14095 |
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Rational design of a novel indole-based microporous organic polymer: enhanced carbon dioxide uptake via local dipole–π interactions
关键字：indole-based microporous organic polymer, local dipole–p interactions
An indole-based microporous organic polymer (PINK) has been obtained by the condensation polymerization of 1,3,5-tris-(4-fluorobenzoyl)benzene with 3,30-diindolylmethane via a catalyst-free nucleophilic substitution reaction. Due to the local dipole–p interactions between indole and carbon dioxide (CO2), the uptake capacity for CO2 reaches up to 16.0 wt% (1.0 bar, 273 K), and the high (CO2/N2),...
http://www.polymer.cn/research/sy_info19478 |
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