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Studies on Cure Kinetics of Poly(phenylene ether)/Epoxy Resin System Using an Advanced Iso-Conversional Method
writer:Wen Xiufang,Wang Wei,Cai Zhi-Qi, Pi Pihui, Zheng Dafeng, Dong Xin, Cheng Jiang,Yang Zhuoru
keywords:Cure kinetics, Epoxy resin, Poly(phenylene ether)
source:期刊
specific source:POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING卷: 50 期: 15 页: 1515-1518
Issue time:2011年
The kinetics and mechanism of poly(phenylene ether)/epoxy resin (PPE/EP) cure system were investigated using an advanced iso-convensional method (AICM). The curing experiments of a PPE/EP cure system with different PPE/EP ratios were carried out by means of non-isothermal differential scanning calorimetry (DSC) with different heating rates of 5, 10, 15 and 20 degrees C/min. From the DSC curves, it was shown that the curing mechanism of PPE/EP is very complicated, and PPE content affects most cure kinetic parameters. A variation of the effective activation energy with the extent of conversion was obtained by AICM and analyzed.