相关链接
联系方式
  • 通信地址:四川省绵阳市涪城区青龙大道中段59号
  • 邮编:621010
  • 电话:18381697211
  • 传真:
  • Email:gjchang@mail.ustc.edu.cn
当前位置:> 首页 > 论文著作 > 正文
Enhanced carbon dioxide capture in an indolebased microporous organic polymer via synergistic effects of indoles and their adjacent carbonyl groups
作者:Guanjun Chang,* Yewei Xu, Lin Zhang and Li Yang*
关键字:microporous organic polymer, synergistic effect, carbon dioxide, uptake
论文来源:期刊
具体来源:Polym. Chem., 2018, 9, 4455
发表时间:2018年

A carbonyl-functionalized indole-based microporous organic polymer (PKIN) was designed and synthesized in the presence of the FeCl3 catalyst by a facile direct oxidative coupling reaction. Taking advantage of the synergistic effect of indoles and their adjacent carbonyl moieties on carbon dioxide (CO2), the CO2 uptake capacity of the polymer reaches up to 6.12 mmol g-1 (1.0 bar, 273 K) with high gas selectivities, making the polymer a promising microporous material for the application of CO2 separation and capture, and the proposed synergistic effect is expected to be a new rationale for the design of CO2 capture materials.