作者：Ningning Song, Kaixiang Shi, Huaxuan Yu, Hongyan Yao,Tengning Ma, Shiyang Zhu,Shaowei Guan
关键字：Cross-linking, Low dielectric constant, Anti-moisture, Co-polyimide, Tetrafluorostyrol side-group
论文来源：期刊
具体来源：European Polymer Journal
发表时间：2018年

In the present study, a series of pendant-group cross-linkable co-polyimide (Co-PI) films were successfully prepared. Via thermal treatment, the cross-linkable tetrafluorostyrol pendant-groups could induce cross-linking without any chemical additives, resulting in the formation of robust cross-linked structures in the co-polyimide films. The effects of cross-linking and the amount of cross-linkable pendant-groups on the performances of copolyimide films were studied and discussed in detail. After cross-linking, the obtained films showed the significantly lowered dielectric constants, which decreased gradually with increasing amounts of cross-linkable pendant-groups. The best dielectric properties were obtained for cross-linked Co-PI-5 film, which exhibits a dielectric constant as low as 2.48 at 1 MHz. Meanwhile, the cross-linked Co-PI-5 film demonstrated excellent moisture resistance with a water uptake of less than 0.31%. It also exhibited outstanding thermal and dimensional stability, superior chemical resistance, excellent mechanical property and surface planarity. The low dielectric constants, excellent anti-moisture performances and outstanding comprehensive properties make the cross-linked Co-PIs a good candidate for interlayer dielectrics in the near future.