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SFPC课题组导热高分子复合材料研究成果发表在Chinese Journal of Polymer Science上

Teng-Bo Ma, Hao Ma, Kun-Peng Ruan, Xue-Tao Shi*, Hua Qiu, Sheng-Yuan Gao and Jun-Wei Gu*. Thermally conductive polylactic acid composites with superior electromagnetic shielding performances via 3D printing technology. Chinese Journal of Polymer Science, 2022, 10.1007/s10118-022-2673-9. 2020IF=3.603.(2区化学类期刊,中国科技期刊卓越行动计划-梯队类期刊项目)

https://doi.org/10.1007/s10118-022-2673-9

Abstract

This work proposes a facile fabrication strategy for thermally conductive graphite nanosheets/polylactic acid sheets with ordered GNPs (o-GNPs/PLA) via fused deposition modeling (FDM) 3D printing technology. Further combination of o-GNPs/PLA with Ti3C2Tx films prepared by vacuum-assisted filtration were carried out by “layer by layer stacking-hot pressing” to be the thermally conductive Ti3C2Tx/(o-GNPs/PLA) composites with superior electromagnetic interference shielding effectiveness (EMI SE). When the content of GNPs was 18.60 wt% and 4 layers of Ti3C2Tx (6.98 wt%) films were embedded, the in-plane thermal conductivity coefficient (λ//) and EMI SE (EMI SE//) values of the thermally conductive Ti3C2Tx/(o-GNPs/PLA) composites significantly increased to be 3.44 W/(m·K) and 65 dB (3.00 mm), increased by 1223.1% and 2066.7%, respectively, compared with λ// (0.26 W/(m·K)) and EMI SE// (3 dB) of pure PLA matrix. This work offers a novel and easily route for designing and manufacturing highly thermally conductive polymer composites with superior EMI SE for broader application.

以聚乳酸(PLA)为基体,石墨纳米微片(GNPs)为导热填料,采用熔融沉积成型(FDM)3D打印技术制备GNPs有序排列的GNPs/PLA(o-GNPs/PLA)片材,与真空辅助抽滤法制备的导电Ti3C2Tx薄膜复合,经“层层铺叠-热压”工艺制备Ti3C2Tx/(o-GNPs/PLA)导热电磁屏蔽复合材料。当GNPs质量分数为20 wt%时,o-GNPs/PLA导热复合材料具有最佳的综合性能,其拉伸强度、熔体体积流动速率和面内热导率(λ//)分别为47.5 MPa、13 cm3/(10 min)和2.90 W/(m·K),是相同GNPs用量下共混热压制备r-GNPs/PLA导热复合材料λ//(1.82 W/(m·K))的1.6倍。引入4层Ti3C2Tx(6.98 wt%)薄膜后,Ti3C2Tx/(o-GNPs/PLA)导热电磁屏蔽复合材料的λ//和面内电磁屏蔽效能(EMI SE//)快速提升至3.44 W/(m·K)和65 dB(3.00 mm),较纯PLA的λ//(0.26 W/(m·K))和EMI SE//(3 dB)分别提升了1223.1%和2066.7%。

论文创新点

1. 采用3D打印技术成功实现了GNPs的有序排列,显著提高了有序排列GNPs/PLA(o-GNPs/PLA)导热复合材料的面内导热系数(λ//);

2.将o-GNPs/PLA与Ti3C2Tx薄膜优化复合,经“层层铺叠-热压”工艺实现了Ti3C2Tx/(o-GNPs/PLA)复合材料的高导热和优异的电磁屏蔽性能。