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[Compos. Sci. Technol.]Interfacial RAFT polymerization induced ultra low dielectric loss ceramic/cyanate ester composites
作者:Yusheng Tang, Shuang Xu, Yunchuan Xie*, Junwei Gu**, Zhimei Song, Feng Gao, Jie Kong
关键字:Surface initiated polymerization, RAFT, Ultra low dielectric loss, Ceramic/cyanate ester composites
论文来源:期刊
具体来源:Composites Science and Technology
发表时间:2016年

Surface initiated reversible addition-fragmentation chain transfer polymerization (RAFT) of glycidyl methacrylate (GMA) was conducted on ceramic particles (ZNT). Then the ZNT@PGMA particles were introduced into cyanate ester (CE) matrix to prepare the ultra low dielectric loss ZNT@PGMA/CE composites. The ZNT@PGMA particles can be well dispersed in the CE matrix, resulting in the improvement of glass transition temperature by 40 oC and the increase of storage modulus by 130% in comparison to that of pure CE resins. The introduction of ZNT@PGMA particles can obviously decrease dielectric loss value of the ceramic/CE composites by one order of magnitude, which possesses potential in wave transparent composites and structures.

http://www.sciencedirect.com/science/article/pii/S0266353816300069