Bis-urea macrocycles with a deep cavity.
writer:Guobao Huang,# Zhenfeng He,# Chenxi Cai, Wei Jiang*
keywords:Bis-urea macrocycles ,molecular recognition
source:期刊
specific source:Chem. Comm., 2015, 51, 15490?15493
Issue time:2015年
Two configurational isomers of bis-urea macrocycles have been synthesized, and their neutral molecule recognition was studied by X-ray crystallography and 1H NMR experiments. Cooperative action between the deep cavity and the urea groups and the influence of dipole alignments on molecular recognition are discussed.