Supramolecular porous ionic network based on triazinonide and imidazolium: a template-free synthesis of meso-/macroporous organic materials via a one-pot reaction-assembly procedure
writer：Hei, Z., Song, G., Zhao, C., Fan, W. and Huang, M.*
keywords：SPINs, ionic porous materials, CO2 uptake
source：期刊
Issue time：2016年
A supramol. porous ionic network (SPIN-1) was designed and prepd. using a one-pot procedure, involving the quaternization of triimidazole triazine with cyanuric chloride followed by hydrolysis and in situ assembly. The structure of SPIN-1 was characterized by FT-IR, solid-state 13C CP/TOSS NMR, elemental anal. and XPS. SPIN-1 shows a BET surface area up to 263 m2 g-1 (av. pore size 11 nm), and a CO2 capture capacity of 24.7 cm3 g-1, which is competitive for Carbon Capture and Storage (CCS). [on SciFinder(R)]