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Core-Cross-Linked Micellar Nanoreactors for Biaryl Synthesis in Water: Influence of Topological Structures on Catalytic Activity
作者:Yue Wang, Yicen Ge,* Yu Long, Meiling Xiang, Xiaoyan Ma, Jinghua Tang, Jinyu Liu, and Keling Hu*
关键字:Core-Cross-Linked Micelle, Suzuki-Miyaura Cross-coupling, Topological Structure
论文来源:期刊
具体来源:Macromolecular Rapid Communications
发表时间:2025年

Multiple block copolymers bearing PDMAEMA (poly(2-(dimethylamino)ethyl methacrylate), PLMA (poly(lauryl methacrylate), and PAMA (poly(allyl methacrylate) segments are synthesized via RAFT (reversibleaddition-fragmentation chain transfer) polymerization. Manipulating the cross-linkage of PAMA in the specific domain of polymeric assemblies affords micellar nanoreactors with different topological structures. After embedded with Pd NPs (nanoparticles) in the corona layer, the core-cross-linked micelles demonstrate profound catalytic activity and structural stability in the aqueous Suzuki–Miyaura coupling of aryl bromides with aryl boronic acids.