Multicompartment micellar aggregates of linear ABC amphiphiles in solvents selective for the C block: a Monte Carlo simulation
writer:Yutian Zhu; Haizhou Yu; Yongmei Wang; Jie Cui; Weixin Kong; Wei Jiang
keywords:ABC amphiphile, multicompartment micelle, Monte Carlo, self-assembly, block copolymer
source:期刊
specific source:Soft Matter, 2012, 8, 4695
Issue time:2012年
采用Monte Carlo方法研究了线性ABC两亲性分子在C嵌段选择性溶剂中的自组装行为。模拟发现了大量多间隔胶束结构,获得了不同嵌段长度ABC两亲性分子的详细相图。结果表明,胶束结构主要受嵌段长度、溶剂质量和不同嵌段间的不相容性控制。通过调节溶剂质量或嵌段间不相容性,观察到多种形态转变。
We applied the Monte Carlo method to study the self-assembly of linear ABC amphiphiles. A great number of multicompartment micelles are discovered and detailed phase diagrams are obtained. The micellar structure is largely controlled by block length, solvent quality, and incompatibility between different block types.
论文链接:https://doi.org/10.1039/c2sm07324b