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11. (Adv. Mater.) A Novel, Luminescent, Silica‐Sol–Gel Hybrid Based on Surfactant‐Encapsulated Polyoxometalates
作者:Wei Qi, Haolong Li, Lixin Wu*
关键字:Encapsulation, Luminescence, Metal-organic materials, Silica, Sol-gels
论文来源:期刊
具体来源:Advanced Materials 2007, 19, 1983-1987
发表时间:2007年

A modified sol–gel approach is used for the preparation of stable silica materials based on a surfactant-encapsulated polyoxometalate (see figure, top panel). In this hybrid material, the luminescence properties of the polyoxometalate and the processibility of the sol–gel matrix are synergistically combined (see figure, bottom panel). This method is, in principle, applicable to all varieties of polyoxometalates, and the resulting composites could be used for applications in optics and catalysis.

http://onlinelibrary.wiley.com/doi/10.1002/adma.200602430/abstract?deniedAccessCustomisedMessage=&userIsAuthenticated=false