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Copolymerization of Carbon Dioxide and Propylene Oxide with Ln(CCl3COO)3-Based catalyst: the Role of Rare Earth Compound in the Catalytic System, J Polym Sci, Part A: Polym Chem, 2001, 39(16), 2751-2754
writer:Binyuan Liu, Xiaojiang Zhao, Xianhong Wang*, Fosong Wang
keywords:CO2, PO
source:期刊
specific source:J Polym Sci, Part A: Polym Chem, 2001, 39(16), 2751-2754.
Issue time:2001年

A highly alternative copolymer of carbon dioxide and propylene oxide was
obtained using a lanthanide trichloroacetates-based ternary catalyst. The rare-earth compound in the ternary catalyst was critical to dramatically raise the yield and molecular weight of the copolymer in addition to maintaining a high alternating ratio of the copolymer