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Tuning Metamaterials Nanostructure of Janus Gold Nanoparticle Film for Surface-Enhanced Raman Scattering
writer:Yixuan Du, Wei Wei, Xiaowei Zhang, and Yunbo Li
keywords:Surface-Enhanced Raman Scatter
source:期刊
specific source:https://pubs.acs.org/doi/10.1021/acs.jpcc.8b00676
Issue time:2018年
Large-area metamaterial nanostructures of a Janus gold nanoparticle (AuNP) film decorated with thiol-terminated polymers have been fabricated and tuned at an oil/water interface by a facile and innovative process. The results show that AuNPs had been arrayed with ultrasmall gaps between neighboring particles laminated with polymer which is called a Janus film. This film exhibits a sensitive property for surface-enhanced Raman scattering (SERS) for determination of both hydrophilic methylene blue and hydrophobic thiram. The structure-dependent SERS of the Janus AuNP film has also been confirmed by a finite-difference time domain (FDTD) method