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The formation of silver nanofibres by liquid/liquid interfacial reactions:mechanistic aspects
作者:Kun Luo , Robert A. W. Dryfe
关键字:nanofibres,liquid/liquid interfacial reactions,?mechanistic aspects
论文来源:期刊
具体来源:New Journal of Chemistry
发表时间:2009年

?The liquid/liquid interfacial reaction (LLIR) between silver nitrate in aqueous solution and   ferrocene in organic solution has been investigated: the resultant silver deposit is found to contain  
long, well-defined nanometre scale fibres, together with thin silver nanowire networks. In situ   optical microscopy and ex situ scanning electron microscopy indicate that the 1D growth of the  
interfacial deposits is due to recrystallisation of the structure formed initially. Geometric factors  are found to exert a larger effect on the 1D growth of silver by LLIRs compared to the  
electrochemical mechanism previously suggested by Scholz et al.