writer：Yubing Xiong,* Jingjiang Liu, Yujiao Wang, Hong Wang, and Rongmin Wang
keywords：carbon dioxide fixation, copolymerization, hydrogen bonds, ionic liquids · nanogel
source：期刊
specific source：Angew. Chem. Int. Ed.
Issue time：2012年

ImIL-based CLPNs were facilely prepared by one-step cross-linking copolymerization of geminal dicationic monomers and cross-linkers in selective solvents. Stable CLPN solutions were obtained and the particle sizes could be
fine-tuned by changing the 1·X/cross-linker feed ratio. Therefore, the one-step synthesis herein presented is an efficient method for the preparation of IL-based CLPNs. Moreover, ImIL-based CLPNs are thermosensitive and display reversible, temperature-driven nanogel–macrogel transitions in methanol. ImIL-based CLPNs were also found to be effective catalysts for CO₂ cycloaddition reactions with epoxides, and could be readily separated by filtration, because of their thermosensitive properties. Such attributes make them a robust material platform suitable for a wide range of applications