Amino-functionalized Poly (N-vinylcaprolactam) Derived from Lysine: Sustainable Polymer with Thermo and pH Dual Stimuli Response.
writer：JIA Fan, WANG Shixue, ZHANG Xiaojie, XIAO Chunsheng, TAO Youhua*,WANG Xianhong*.
keywords：Sustainable Polymer
source：期刊
specific source：Polymer Chemistry
Issue time：2016年
Lysine, a renewable feedstock with economic feasibility, was tactfully cyclized to its corresponding cyclic lysine and then subjected to a reaction with acetylenes to yield a sustainable N-vinylcaprolactam (VCL) derivative. Subsequent MADIX/RAFT copolymerization of the resultant monomer gave well-defined PVCL bearing pendant 2,5-dimethylpyrrole protected amino groups with narrow polydispersity.