作者：Zheng, Z (Zheng, Zhi)[ 1 ] ; Wang, JL (Wang, Jianli)[ * ] ; Lu, Z (Lu, Zhen)[ 1 ] ; Luo, M (Lu
关键字：glycerol,2-tosyloxy-1,3-propanediol,1,3-propanediol,hydrogenolysis, Raney Ni
论文来源：期刊
具体来源：JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
发表时间：2013年
摘要: 2-Tosyloxy-1,3-propanediol (TPD), a potential precursor for 1,3-propanediol (1,3-PD) production, is produced by the tosylation of glycerol with the help of protecting group techniques. In this work, the hydrogenolysis of TPD into 1,3-PD over Raney Ni catalyst is discussed at different reaction parameters to optimize the reaction conditions for selective formation of 1,3-PD. The mechanisms of the hydrogenolysis of TPD and the side reactions were also confirmed by gas chromatography-mass spectrometry (GC-MS) technique.