Preparation and catalytic oxidation properties of inorganic polymer encapsulated metal complexes
作者：Rong-Min Wang, Zhen-Lin Zhang, Jian-Fang Lou, Yun-Pu Wang, Peng-Fei Song,Chun-Gu Xia
关键字：catalytic oxidation; molecular sieve; cyclohexene, hexanedialygm
论文来源：期刊
具体来源：POLYMERS FOR ADVANCED TECHNOLOGIES??
发表时间：2004年
An inorganic polymer supporter, such as molecular sieve MCM-41, was used as a support for
encapsulating metal complex catalysts. The metal complex was prepared with L-glutamic acid
and Co(OAc)2. 4H2O. Their catalytic activity in oxidation of cyclohexene with H2O2 was studied.
The major products of this reaction were hexanedial, 2-cyclohexen-1-one, 2-cyclohexen-1-hydropenoxide
and epoxide, which is different from typical oxidation of cyclohexene. The effect of temperature,
solvent, additive, the amount of catalyst and oxidant were also discussed. The catalyst shows
high catalytic activity.