作者：Rong-Min Wang, Er-Xia Hao, Guo-Rui Shen, Yu-Feng He, Zi-Qiang Lei
关键字：polymeric dinuclear metal complex;polyphthalocyanines; salphen schiff base metal complexes;sheet polymer; molecular oxygen; catalytic oxidation
论文来源：期刊
具体来源：Wiley Periodicals Inc. J Appl Polym Sci 111: 1999–2005, 2009
发表时间：2009年

The polymeric Salphen Schiff base-phthalocyanine Co-Cu dinuclear metal complex (PSalphenCo-PcCu) was designed and synthesized through interfacial
condensation polymerization. The new sheet polymeric dinuclear metal complex has been characterized by IR spectra, UV-visible spectra, scanning electron microscopy with energy dispersive X-ray analysis and thermogravimetry
analysis. Its catalytic activity for activation of molecular oxygen was investigated by using cumene as substrate without any additive in mild condition. The aerobic oxidation of cumene catalyzed by PSalphenCo-PcCu proved to be a simple and efficient method for obtaining cumene hydroperoxide in a high selectivity.