30. Phase-separated structures in polymer mixtures with a thermotropic liquid crystalline copolyester as one component: composition dependence
			        作者:Akemi Nakai, Wei Wang, Shigeru Ogasawara, Hirokazu Hasegawa, Takeji Hashimoto
关键字:Phase-separated structures; thermotropic liquid crystalline copolyester
论文来源:期刊
具体来源:Macromolecules
发表时间:1998年
The composition dependence of the phase-separated structures in the  polymer mixtures consisting of a thermotropic liquid crystalline (LC)  copolyester (X-7G) and poly(ethylene terephthalate) (PET) was  investigated by means of polarized light microscopy. For this purpose  the mixtures were solution-cast into thin films, followed by isothermal  annealing at 270 °C. Although the final structure was the LC droplets  dispersed in the isotropic matrix for all mixtures, a variety of  pattern-forming processes were observed, depending on the composition.  For the mixtures with higher X-7G content, dewetting of the X-7G  component on the surface of the glass substrate played an important role  in the pattern formation.