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89. A Click Chemistry Approach to The Efficient Synthesis of Polyoxometalate-Polymer Hybrids with Well-Defined Structures
作者:MinBiao Hu, Nan Xia, Wei Yu, Chi Ma, Jing Tang, Zhan-Yao Hou, Ping Zheng, Wei Wang
关键字:Click Chemistry, Hybrid Polymer, Polyoxometalates
论文来源:期刊
具体来源:Polymer Chemistry
发表时间:2012年

In this study a click chemistry approach was used to synthesize polyoxometalate–polymer hybrids with well-defined structures. The starting materials were a two-azido-containing organosilyl derivative of a Wells-Dawson-type polyoxometalate and a propargyl-terminated poly(ε-caprolactone). The clicking reaction between the azido groups and alkynyl groups was found to be very efficient and the structures of the hybrids were well-defined. This breakthrough will promote a great development in the synthesis of various polyoxometalate–polymer hybrids and broaden their potential application.