writer：Hailan Han, Hai Qiang Li, Meiyu Liu, Lishuang Xu, Jingmei Xu, Shuang Wang, Hongzhe Ni , Zhe Wang
keywords：Crosslinked hybrid membranes,SiO2,Proton exchange membrane,Fuel cells
source：期刊
specific source：Journal of Power Source
Issue time：2017年
A series of novel organic-inorganic crosslinked hybrid proton exchange membranes were prepared using sulfonated poly(arylene ether ketone sulfone) polymers containing carboxyl groups (C-SPAEKS), (3-aminopropyl)-triethoxysilane (KH550), and tetraethoxysilane (TEOS). KH550 acted as a “bridge” after reacting with carboxyl and sulfonic groups of C-SPAEKS to formcovalent and ionic crosslinked structure between the C-SPAEKS and SiO₂ phase. The crosslinked hybrid membranes (C-SPAEKS/K-SiO₂) were characterized by FT-IR spectroscopy, TGA, and electrochemistry, etc. The thermal stability, mechanical properties and proton conductivity of the crosslinked hybrid membranes were improved by the presence of both crosslinked structure and inorganic phase. The proton conductivity of C-SPAEKS/K-SiO₂-8 was recorded as 0.110 S cm^-1, higher than that of Nafion^® (0.028 S cm^-1) at 120 °C. Moreover, themethanol permeability of the C-SPAEKS/K-SiO₂-8 was measured as 3.86 × 10^-7 cm² s^-1, much lower than that of Nafion^® 117 membranes (29.4 × 10^-7 cm² s^-1) at 25 °C.