作者：Wei Ziyu, Zhou Shanshan, Xie Yuhong, Sun Yongyan, Ma Huimin, Xie Zhanghua, Zhu Zhe, Yang Jinjun
关键字：PES, Crystallization, Dual effects, Aggregated structure
论文来源：期刊
具体来源：Polymer Testing
发表时间：2021年

A linear diamides derivative-containing organic compound (TMC306) as a nucleator was incorporated into

biodegradable poly (ethylene succinate) (PES) to investigate effect of TMC306 on crystallization behavior and

aggregated structure of PES. Upon incorporation of TMC306 with lower weight fraction (fTMC306), crystallization

temperature (Tc), crystallization rate (k) and degree of crystallinity (Xc) of PES enhanced significantly and

crystallization half-time (t1/2) reduced substantially. However, Tc, k and Xc declined progressively in the presence

of higher fTMC306. Based on IR results, it suggested that TMC-306 interacts with –C––

O group of PES and C–O–C

group of PES amorphous phase via hydrogen bond. Mechanisms on nucleation of PES and dual effects of TMC306

on crystallization behavior of PES were proposed and discussed in detail.