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Size-controlled Gold Nanocolloids on Polymer Microsphere-stabilizer via Interaction Between Functional Group and Gold Atoms
作者:Wei Liu, Xinlin Yang*, Lei Xie
关键字:Interaction between metallic nanocolloids and functional group, Microsphere-stabilized gold nanocolloids
论文来源:期刊
具体来源:J. Colloid Interface Sci., 313 (2), 493-502 (2007). DOI: 10.1016/j.jcis.2007.04.055
发表时间:2007年
Gold nanocolloids with the controlled diameter ranging from 5.2 to 10.7 nm were in situ prepared by reduction of gold chloride trihydrate with sodium borohydride as reductant via the interaction between the gold naocolloids and the functional groups on the surface of polymer microspherestabilizer. The nature of such interaction was studied in detail by X-ray photoelectron spectroscopy (XPS). The effect of the functional groups on the catalytic activity of the gold nanocolloids was preliminarily investigated with the reduction of 4-nitrophenol to 4-aminophenol in the presence of sodium borohydride as reductant.