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Biomass-derived 3D magnetic porous carbon fibers with a helical/ chiral structure toward superior microwave absorption
作者:Fei Wu, Ke Yang, Qiang Li, Tariq Shah, Mudasir Ahmad, Qiuyu Zhang, Baoliang Zhang *
关键字:Magnetic tubular carbon fibers, Biomass Chiral structure, Microwave absorption, Catalytic self-deposition
论文来源:期刊
具体来源:Carbon
发表时间:2020年

Herein, a catalytic self-deposition (CSD) strategy is proposed to build 3D magnetic porous carbon fibers with a complex helical/chiral structure (MHPFs) toward ultralight and low-frequency microwave absorption unprecedentedly. Different from energy-intensive chemical vapor deposition (CVD) method, the binary composition of cobalt-encapsulated carbon nanotube arrays (CNTAs) and hierarchical pore structure are manipulated by adjusting the CSD technology without exogenous carbon and reducing atmosphere. Micro-/nano-scale structures, 0D/1D integration effects, dielectric/magnetic loss mechanisms, and extraordinary 3D helical/chiral configuration endow MHPFs with remarkable microwave absorption properties. The minimum reflection loss (RLmin) of MHPFs-900 (900 stands for the carbonization temperature) at a low frequency (6.3 GHz) reaches astronomical 61.08 dB. The effective absorption bandwidth (EAB, RL < 10 dB) ranges from 5.4 GHz to 7.5 GHz at a loading of 5%. Notably, at a matching thickness of 2.00 mm, the ultrawide EAB covers 6.2 GHz (11.6e17.8 GHz), while the RLmin exceeds 30.06 dB. Moreover, even with an ultralow filler loading of 2.5%, the absorber still exhibits satisfactory RLmin and broad EAB of 45.04 dB and 4.5 GHz (8.2e12.7 GHz). The results might shed light on the economical and high-producing preparation of advanced microwave absorption materials.