作者：Wu, Defeng，Lin, Dongpo，Zhang, Jie，Zhou, Weidong，Zhang, Ming*，Zhang, Yisheng，Wang, Dongmei，Lin, Bil
关键字：none
论文来源：期刊
具体来源：Macromolecular Chemistry and Physics
发表时间：2011年
Adding nanofillers to PLA/PCL blends to change their surface and interface properties can improve their phase morphology. Here the selective localization of CNTs and organoclays as the third component in the blend is studied. It is found that clay is selectively localized in the PLA phase and at the phase interface whereas CNTs are mainly found in the PCL phase and at the phase interface. With a reduced viscosity ratio of the blend matrices, the CNTs change their preferred localization from PCL to PLA. The effects of the different selective localization of clay and CNTs on the morphologies are studied. In addition, the crystallization behavior of ternary systems also shows a strong dependence on the selective localization of nanofillers.