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Inclusion complexation of diphenylamine-4-diazonium chloride and p-sulfonato-calix [4] arene
作者:Yongjun Zhang, Guangzhong Tu, Weixiao Cao*
关键字:host-guest chemistry
论文来源:期刊
具体来源:Supramolecular Chemistry, 2002, 14, 473-475.
发表时间:2002年

Inclusion complexation of p-sulfonatocalix[4]arene (SC4A) and diphenylamine-4-diazonium chloride (DDC) in aqueous solution was investigated in this study. The inclusion of DDC in the cavity of SC4A leads to H-1 NMR chemical shifts of DDC moving towards higher magnetic field. The complexation of SC4A also results in a bathochromic shift and a decrease in optic intensity of the absorption spectrum of DDC. In the presence of SC4A, the thermal stability of DDC in aqueous solution increases significantly while its photosensitivity still remains high.