A Linear-Hyperbranched Supramolecular Amphiphile and Its Self-Assembly into Vesicles with Great Ductility
writer：Tao, W.; Liu, Y.; Jiang, B. B.; Yu, S. R.; Huang, W.; Zhou, Y. F.*; Yan
keywords：Linear-Hyperbranched Supramolecular, Self-Assembly
source：期刊
specific source：J. Am. Chem. Soc. 2012, 134, 762. http://pubs.acs.org/doi/pdf/10.1021/ja207924w
Issue time：2012年
A linear-hyperbranched
supramolecular amphiphile was synthesized through the noncovalent coupling of
adamantane-functionalized long alkyl chain (AD-Cn, n =
12, 18, 30) and hyperbranched polyglycerol grafted from β-cyclodextrin
(CD-g-HPG) by the specific AD/CD host–guest interactions. The obtained
supramolecular Cn-b-HPGs self-assembled into
unilamellar vesicles with great ductility that could be disassembled readily
under a competitive host of β-CD.