Quantitative Dependence of Crystallinity on Degree of Branching for Hyperbranched Poly[3-ethyl-3-(hydroxymethyl)oxetane]
writer:Mai, Y. Y.; Zhou, Y. F.*; Yan, D. Y.*; Hou, J.
keywords:Crystallinity, Hyperbranched Poly[3-ethyl-3-(hydroxymethyl)oxetane]
source:期刊
specific source:New J. Phys. 2005, 7 (42) http://iopscience.iop.org/1367-2630/7/1/042/pdf/1367-2630_7_1_042.pdf
Issue time:2005年
A series of hyperbranched poly[3-ethyl-3-(hydroxymethyl)oxetane]
samples with various degrees of branching (DB) were adopted to investigate the
relationship between crystallinity and DB. The relative degree of crystallization
(DC) and DB were determined by x-ray diffraction (XRD) and 13C nuclear
magnetic resonance (13C-NMR) measurements, respectively. The corresponding
plot of DC versus DB shows quantitative dependence of the crystallinity on DB
for the polyether.