- A Platform for Preparation of Monodispersed Fluorescent Conjugated Polymer Microspheres with Core-shell Structures
- 来源：范丽娟教授个人网站
2013-09-04
- A strategy to prepare stable monodispersed fluorescent microspheres is developed by modifying the Wessling method to synthesize poly(p-phenylenevinylene) (PPV) on the surface of a highly crosslinked polymer core. The positively charged PPV polymer precursors (pre-PPV) are adsorbed onto the core with negative charges on the surface and then the insoluble fluorescent PPVs form after thermal elimination. Each individual sphere is found to possess a very smooth surface with an even distribution of fluorescence by microscopic techniques. Very small coeffi cient of variance (CV) values of emission intensity ( < 4.0%) and size ( < 2.3%) are realized for microspheres prepared in the same batch. The spheres are demonstrated to have good thermal stability and photostability.
- [来源：中国聚合物网]