- Atom transfer radical polymerization of glycidyl methacrylate followed by amination on the surface of monodispersed highly crosslinked polymer microspheres and the study of cation adsorption
- 来源:范丽娟教授个人网站
2014-09-17
- The introduction of reactive groups on the surface of monodispersed highly crosslinked poly(styrene–divinylbenzene) (PSDVB) microspheres was accomplished in two steps. The first step requires immobilizing the initiating groups by a Friedel–Craft acylation between 2-chloropropionyl chlorides and the phenyl groups on the spheres. The second step requires the atom transfer radical polymerization (ATRP) of glycidyl methacrylate (GMA) to obtain spheres (PSDVB-g-PGMA) with epoxy groups on the surface. To demonstrate the feasibility of introducing functionality, the epoxy groups were ring-opened by ethylenediamines, resulting in spheres with amino functionality (PSDVB-g-PGMAEDA). The final spheres were found to have an adsorption capacity of 0.66 mmol/g in the Cu2+ adsorption experiments, as a preliminary application study.
- [来源:中国聚合物网]