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Applied Chemometrics, Analytical Chemistry & Sampling Research Group (应用化学计量学、分析化学与取样研究组ACACSRG)
【简介】Chemometrics - Data analytical IT-discipline used for characterization of "hidden information" from scientific-, industrial-, production- and laboratory data etc. This is achieved by modelling the so-called latent data structures by use of very "open" methods and algorithms - multivariate data analysis - so that the most informative variations (variances, covariances) are accentuated (PCA,...
http://www.polymer.cn/resource/11402resource.html |
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Syntheses and second-order nonlinear optical properties of a series of new “H”-shape polymers
关键字：Click chemistry, H-type chromophore, Nonlinear optics,Synthesis, Suzuki coupling copolymerization, Suitable isolation group
To develop more “H”-shape nonlinear optical polymers, in this paper, four new polymers embedded with “H”-type chromophore moieties were designed and synthesized through a Suzuki coupling copolymerization reaction. The “H”-type chromophores were easily prepared by the utilization of “Click Chemistry” reactions, and their structures could be conveniently adjusted by changing the diazido gr...
http://www.polymer.cn/research/sy_info17358 |
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Using Two Simple Methods of Ar-ArF Self-Assembly and Isolation Chromophores to Further Improve the Comprehensive Performance of NLO Dendrimers**
关键字：isolation chromophores, click chemistry, dendrimers, nonlinear optics, self-assembly
Herein, through a combination of divergent and convergent approaches, coupled with the utilization of the powerful Sharpless “click chemistry” reaction, two series of high-generation nonlinear optical (NLO) dendrimers have been conveniently prepared in high purity and satisfactory yields. Perfluoroaromatic rings and isolation chromophores were intro...
http://www.polymer.cn/research/sy_info17327 |
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Synthesis of three-arm poly(ethylene glycol) by combination of controlled anionicpolymerization and ‘click’ chemistry
关键字：controlled anionic polymerization, ‘click’ chemistry,three-arm poly(ethylene glycol),synthesis
Poly(ethylene glycol) (PEG) is an important water-soluble polymer, which is widely used in the biomedical field because
of its good biodegradability, biocompatibility and permeability. It is usually synthesized by anionic polymerization of
ethylene oxide but side reactions lead to the formation of some oligomers. High molecular weight PEG can be obtained,
however, through coordinated anionic po...
http://www.polymer.cn/research/sy_info14795 |
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Journal of Polymer Science Part A: Polymer Chemistry 2012, 50(3), 571
关键字：ring-opening polymerization (ROP); reversible addition-fragmentation chain transfer (RAFT); controlled/“living” radical polymerization; star polymer
Reversible addition-fragmentation chain transfer (RAFT) polymerization is a more robust and versatile approach than other living free radical polymerization methods for synthesis of well-defined homo-, gradient, block, star-shaped and more complex structural polymers, like micro(nano)gels and polymer brushes. Thus the resultant polymers with thiocarbonylthio-terminated groups are readily tailored ...
http://www.polymer.cn/research/sy_info14739 |
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Journal of Polymer Science Part A: Polymer Chemistry 2012, 50(3), 571
关键字：controlled ring-opening polymerization (CROP); reversible addition-fragmentation chain transfer (RAFT); "living"/controllable polymerization; star block copolymer;
Reversible addition-fragmentation chain transfer (RAFT) polymerization is a more robust and versatile approach than other living free radical polymerization methods for synthesis of well-defined homo-, gradient, block, star-shaped and more complex structural polymers, like micro(nano)gels and polymer brushes. Thus the resultant polymers with thiocarbonylthio-terminated groups are readily tailored ...
http://www.polymer.cn/research/sy_info14683 |
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化学还原法合成硫化铅纳米棒及其表征
关键字：semiconductor, lead sulfide, nanorods, chemistry reduction
PbS nanomaterials possess versatile specially optical and electronic properties. A lot of efforts have been made to preparePbS nanomaterials with different morphology. In the paper, PbS nanorods were prepared by using a chemistry reduc...
http://www.polymer.cn/research/dis_info6628 |
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Design and Synthesis of Star Polymers with Hetero-arms by the Combination of Controlled Radical Polymerizations and Click Chemistry
关键字：Design,Synthesis,Star,Polymers,Hetero,arms,Combination,Controlled,Radical,Polymerizations,Click,Chemistry,
Star-branched polymers have been widely studied for a long time from both synthetic and theoretical viewpoints.
http://www.polymer.cn/research/dis_info5993 |
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“链接”化学(Click Chemistry)原位制备温度敏感水凝胶
关键字：：“链接”化学，温度敏感，水凝胶
“链接”化学(Click Chemistry)，又称1,3-偶极环加成反应，是由Sharpless等[1]首先提出的，其宗旨是提出一种以含杂原子链接单元C–X–C为基础的组合化学新方法；用少量简单可靠和高选择性的化学转变来获得更多样化的分子, 开创了快速、有效、甚至是100%可靠的、高选择性地制备各类新型化合物的新领域。目前，在高分子合成化学领域内，它已被视为一种快捷高效的途径来链接不同的高分子链，达到制备嵌段、梳状及超支化等聚...
http://www.polymer.cn/research/dis_info4179 |
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Syntheses and second-order nonlinear optical properties of a series of new “H”-shape polymers
关键字：Click chemistry, H-type chromophore, Nonlinear optics,Synthesis, Suzuki coupling copolymerization, Suitable isolation group
To develop more “H”-shape nonlinear optical polymers, in this paper, four new polymers embedded with “H”-type chromophore moieties were designed and synthesized through a Suzuki coupling copolymerization reaction. The “H”-type chromophores were easily prepared by the utilization of “Click Chemistry” reactions, and their structures could be conveniently adjusted by changing the diazido gr...
http://www.polymer.cn/research/sy_info17358 |
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