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A Heterotetranuclear Metal Complex {Ni2Na2} with Azido Bridges
The reaction of Ni(ClO4)2·6H2O with 3-ethoxy-2-hydroxybenzaldehyde
(Hemp), methylamine, and NaN3 in DMF solution, under solvothermal conditions, leads to the formation of the heterotetrametallic cluster [Ni2Na2(μ1,1,1-N3)2(emimp)4(DMF)2] (I) (emimp = 2-ethoxy-6-formyl-phenolate anion, DMF = N,N-dimethyl-formamide). Compound I displays dominant ferromagnetic interactions through μ1,1,1-N3 bridg...
http://www.polymer.cn//ss/zhangshuhua/publicationsshow_4694.html |
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2,Fast Response and High Sensitivity Europium Metal Organic
Iron is one of the most important elements in
the metabolic process for all living system. However, both its
deficiency and excess from normal permissible limits can
induce serious disorders. We synthesized a europium-based
metal−organic framework (Eu-MOF), EuL3
(L =4′-(4-carboxyphenyl)-2,2′:6′,2″-terpyridine), under hydrothermal
conditions, and used it as a sol...
http://www.polymer.cn//ss/ciacxie/publicationsshow_4393.html |
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A strategy to immobilize noble metal nanoparticles on silica microspheres
www.sciencedirect.com/science/article/pii/S1381116910002335
A strategy to immobilize noble metal nanoparticles on silica microspheres is proposed. Following this strategy, 350 nm silica microspheres synthesized by Stöber method are initially activated with 3-(trimethoxysilyl) propyl methacrylate to anchor CC bonds on the surface of the silica microspheres. Then a thin layer of coordination p...
http://www.polymer.cn//ss/zhangwangqing/publicationsshow_4024.html |
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Generation of Polymer-metal Hybrid Nanostructures by Reduction of Metal Ions in Polyelectrolyte Complexes Using Radiation Approaches
Polymer metal hybrid nanomaterials are potentially useful for a wide range of applications, including sensors, catalytic systems, optical materials, elements of microcircuits, protective coatings etc.
http://www.polymer.cn/research/dis_info16069 |
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Synthesis and characterization of transition metal-containing polyamides
关键字：transition metal, coordination complex, polycondensation, polyamide
Well-characterized metal-containing polymers have led to a rapidly expanding interest in their properties and potential applications. The incorporation of metal atoms into synthetic polymer chains leads to macromolecular structures in which meta...
http://www.polymer.cn/research/dis_info11680 |
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Applying Scientific Methods to Develop the Next Generation of Aqueous Rubber to Metal Adhesives
关键字：aqueous rubber to metal bonding adhesive
Specialized bonding agents are the critical components ofsome of the most sophisticated rubber assemblies beingmanufactured today. Rubber-to-metal bonded assembliesare widely encountered in a range of mechanical goodsfrom the very simple to high...
http://www.polymer.cn/research/dis_info9236 |
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SYNTHESIS AND CHARACTERIZATION OF POLYMER MICROBEAD FOR METAL AFFINITY CHROMATOGRAPHY
关键字：SYNTHESIS,AND,CHARACTERIZATION,POLYMER,MICROBEAD,FOR,METAL,AFFINITY,CHROMATOGRAPHY,
The development of techniques and methods for the separation and purification of proteins has been essential for many of the recent advancements in biotechnology andbiomedical research .
http://www.polymer.cn/research/dis_info5614 |
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A NEW FLAT TRANSITION METAL CATALYST FOR STYRENE POLYMERIZATION
关键字：NEW,FLAT,TRANSITION,METAL,CATALYST,FOR,STYRENE,POLYMERIZATION,
Studies of the oxidative chemistry of nickel porphyrins span more than three decades[1] and current interest in the oxidative chemistry of nickel porphyrins is prompted by the original identification of nickel tetrapyrole, factor 430&n...
http://www.polymer.cn/research/dis_info1726 |
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Stepwise Metal Assembling of Gold Clusters with the DPA Dendrons
关键字：Stepwise,Metal,Assembling,Gold,Clusters,DPA,Dendrons,
Metal nanoparticles exhibit unique characteristics that are not observed in bulk metals. Some functional groups have been engaged into modify nanoparticles, which leads to some new properties.
http://www.polymer.cn/research/dis_info832 |
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SYNTHESIS AND METAL-CATALYZED POLYMERIZATION OF AMINOPROPYNE DERIVATIVES
关键字：SYNTHESIS,AND,METAL,CATALYZED,POLYMERIZATION,AMINOPROPYNE,DERIVATIVES,
Nitroxide and aminium radicals are stable at ambient conditions and display magnetic and electrochemical properties derived from their unpaired electrons1. Poly(3-N-tert-butylnitroxide-1-propyne) 1 and poly(dianisylaminiumacetylene) 2 were designed and synthes...
http://www.polymer.cn/research/dis_info811 |
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