| |
Solvothermal Metal Metathesis on a Metal?Organic Framework with Constricted Pores and the Study of Gas Separation
Metal?organic frameworks (MOFs) with constricted pores can
increase the adsorbate density of gas and facilitate effective CO2 separation from
flue gas or natural gas due to their enhanced overlapping of potential fields of the
pores. Herein, an MOF with constricted pores, which was formed by narrow
channels and blocks of functional groups, was fabricated from the assembly of a
met...
http://www.polymer.cn//ss/zhaoxuebo/publicationsshow_9863.html |
| |
Tuning the Structure of Metal Phosphonate Using Uncoordinating Methyl group: Syntheses, Structures and Properties of a Series of Metal Diphosphonates
Eight new transition metal diphosphonates, namely, [Mn(H2L)(H2O)2][(H2O)2] (1), [Co(H2O)6][H2L][(H2O)2] (2), [Co(H2O)6][(H3L)2][(H2O)2] (3), [Ni(H2O)6][H2L][(H2O)2] (4), [Cu(H2L)][(H2O)2] (5), [Zn(H2O)6][(H3L)2][(H2O)2] (6), [Zn(H2L)(H2O)2] (7) and [Cd(H2L)(H2O)2] (8), have been synthesized hydrothermally from 2,5-dimethyl-1,4-phenylenediphosphonic acid (H4L) and thoroughly characterized using EA,...
http://www.polymer.cn//ss/zhaoxuebo/publicationsshow_9857.html |
| |
Infinite Metal–Carboxylate Nanotube Constructed Metal–Organic Frameworks and Gas Sorption Properties
Two isomorphic microporous metal–organic frameworks (MOFs), [Co2L(H2O)2]·4.5H2O (1) and [Ni2L(H2O)2]·3.5H2O (2), were synthesized by the reaction of an aminopolycarboxylate ligand (H4L) with Co and Ni hydroxides under hydrothermal conditions. The exquisite assembly of the carboxylate, imino groups, and metal ions resulted in a 1D special nanotube that could be used as a blueprint fo...
http://www.polymer.cn//ss/zhaoxuebo/publicationsshow_9837.html |
| |
Li3–O–Li3 molecule: A metal-nonmetal-metal sandwichlike compound with a distending electron cloud
The D3d and D2d isomers of the Li3–O–Li3 molecule are metal-nonmetal-metal sandwichlike
structures that contain two Li3 superalkali atoms. Their geometries and the real frequencies are
obtained at the CCSDT/aug-cc-pVDZ level.
http://www.polymer.cn//ss/LiZhiru/publicationsshow_3526.html |
| |
Series of Metal-Nonmetal-Metal Sandwich Compounds: Out-of-Plane σ-Aromaticity and Electric Properties
A new class of metal-nonmetal -metal sandwich structures M3-CO3-M3
′ (M, M ′ ) Li, Na, K) with all real
frequencies is obtained at the MP2 method with the 6-311 +G (2d) basis
set.
http://www.polymer.cn//ss/LiZhiru/publicationsshow_3524.html |
| |
201. Electrospun Fibrous Membranes for Efficient Heavy Metal Removal.
关键字：adsorption, electrospinning, membranes
Heavy metal pollution is a growing environmental problem in recent decades, which requires immediate and urgent action. In this article, we provide an overview of the works published in the last decade concerning the development of electrospinning-based micro- and nano-porous membranes for efficient heavy metal removal. Apart from their super-high surface-to-volume ratio, electrospun nanofibers po...
http://www.polymer.cn/research/sy_info18187 |
| |
Double metal cyanide complexes: versatile and highly active catalysts for C-O(S) bondinvolved polymerizations
Double metal cyanide complex (DMCC, or DMC) is an inorganic coordinated polymer with three-dimensional network, in which the inner metal MII is linked with the external metal MI by several cyano-bridges (MII－C≡N－MI, generally, MI&nb...
http://www.polymer.cn/research/dis_info16747 |
| |
Hybrid core-shell nanoparticles with metal-enhanced fluorescence effects
Recent years have witnessed a growing interest in core-shell hybrid nanoparticles. It is typically involves coating the surface of particles with a special shell, so as to modify the surface properties of the core component.
http://www.polymer.cn/research/dis_info16612 |
| |
Synthesis of Nylon 3 by Ring Opening Polymerization with a Metal-free Catalyst
Nylon 3 or polyamide 3 with a -amino acid skeleton, which is different from other commercial nylons in the amide linkages, usually exhibits interesting properties such as high capacity of moisture up-take, high glass trans...
http://www.polymer.cn/research/dis_info16131 |
| |
Glass Transition and Melting Behavior of the Interface between Polyacrylates and Metal
The surface and interfacial interaction of polymers has attracted interests for the interfacial interaction dominates the adhesion, durability and bio-compatibility of polymer materials.
http://www.polymer.cn/research/dis_info12967 |
| |