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(Polymer) UV-thermal Dual Cured Anti-bacterial Thiol-ene Networks with superior performance from Renewable Resources
Bio-based anti-bacterial cross-linked films with superior properties were prepared via UV-thermal induced thiol-ene “click” reaction of diallyl itaconate (DAI), eugenol allyl ether (EAE) with trimethylolpropane tris (3-mercaptopropionate). DAI and EAE were made from one-step reaction of itaconic acid and eugenol with allyl bromide, respectively. The curing behaviors studied by Fourier transfor...
http://www.polymer.cnt//ss/masongqi/publicationsshow_9790.html |
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(Prog. Org.Coat.)Synthesis of bio-based unsaturated polyester resins and their application in waterborne UV-curable coatings
In this paper, three bio-based unsaturated polyesters were synthesized from itaconic acid and different diols which could be derived from renewable resources. Their chemical structures were confirmed by FT-IR, 1H NMR and acid value as well as hydroxyl value. Waterborne UV curable networks based on these polyesters were manufactured and their mechanical properties, thermal stability and coating p...
http://www.polymer.cnt//ss/masongqi/publicationsshow_9701.html |
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(Prog. Org. Coat.)High Bio-based content waterborne UV-curable coatings with excellent adhesion and flexibility
A series of bio-based unsaturated polyesters was synthesized by melt polycondensation of itaconic acid with 1,4-butanediol and glycerol. Their chemical structures were confirmed by FT-IR, 1H NMR, acid and hydroxyl values. Waterborne UV curable dispersion coatings based on these polyesters and acrylated epoxidized soybean oil (AESO) were formulated. The average particle size and their stability b...
http://www.polymer.cnt//ss/masongqi/publicationsshow_9700.html |
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植物油基紫外光(UV)固化涂料研究进展
植物油基紫外光(UV)固化涂料以可再生的植物油为原料,结合具有高效、节能、环保等特点的 UV 固化技术,已受到业界的广泛关注,并且取得了一定的研究进展。 文章从干性油、巯基-烯结合植物油、(甲基)丙烯酸酯植物油、马来酸酐改性植物油、环氧植物油等方面介绍了国内外植物油基 UV 固化涂料的研究进展及发展趋势。
http://www.polymer.cnt//ss/masongqi/publicationsshow_9697.html |
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Fixation of carbon dioxide concurrently or in tandem with free radical polymerization for highly transparent polyacrylates with specific UV absorption
It is still a challenging issue to combine the coupling reaction and free radical polymerization (FRP) for well-controlled and efficient synthesis of polyacrylates bearing the cyclic carbonate group from carbon dioxide (CO2) and vinyl epoxides. This work describes the efficient catalytic synthesis of poly(2-oxo-1,3-dioxolane-4-yl)methyl methacrylate (PDOMA) from CO2 and glycidyl methac...
http://www.polymer.cnt//ss/xhzhang/publicationsshow_9291.html |
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Functionalization of cotton fabric with graphene oxide nanosheet and polyaniline for conductive and UV blocking properties
Multifunctional cotton fabric with high electrical conductivity and ultrastrong UV radiation protection properties was successfully fabricated by coating graphene oxide (GO) nanosheet dispersion on fabric surface via vacuum filtration deposition (VFD) method, and then the treated fabric was assembled with polyaniline (PANI) by in-situ chemical polymerization process. The structure and morphologica...
http://www.polymer.cnt//ss/qulijun/publicationsshow_8902.html |
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Enhanced thermal, UV blocking and dye absorptive properties of chitosan/poly (vinyl alcohol)/graphene oxide fibers
Ductile appearance, remarkable length-diameter ratio, flexible fabrication properties and featured additional functions of functional composite fibers elicit great interest in applications. In this paper, chitosan/poly(vinyl alcohol) composite fibers with different graphene oxide additive (1-7 wt.%) were spun via continuous wet-spinning route and the resultant fibers revealed improved thermal, UV ...
http://www.polymer.cnt//ss/qulijun/publicationsshow_8891.html |
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An UV-curable epoxy acrylate oligomer with high refractive index containing fluorene: Preparation, characterization, and application
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http://www.polymer.cnt//ss/fchem/publicationsshow_8571.html |
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Polymer Chemistry 2015: Real Time Quantification of the Chemical Cross-Link Density of a Hydrogel by in situ UV-vis Spectroscopy
In this paper, we prepare a hydrogel in a green way via the redox reaction between phenol groups and EosinY by visible light irradiation. Eosin Y shows significant absorption at 515 nm while the reduced product does not. A series of control experiments show that almost 100% of the consumed Eosin Y is reacted with phenol groups to form cross-link points. On the basis of the two results, the chemica...
http://www.polymer.cnt//ss/cuishuxun/publicationsshow_8343.html |
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[2014][J. Mater. Chem. C, 2014,2: 2431-2438]Panchromatic Small Molecules for UV-Vis-NIR Photodetectors with High Detectivity
Two donor–acceptor–donor (D–A–D) type low-bandgap small molecules, M1 and M2, with bis(2-thienyl)-N-alkylpyrrole (TPT) as the donor and thieno[3,4-b]thiadiazole (TT) as the acceptor were designed and synthesized. The absorption, transmission, electrochemical, thermal and film properties were studied. The compounds showed panchromatic absorption in the spectral range of 300–1000 nm. Moreover...
http://www.polymer.cnt//ss/qiaowenqiang/publicationsshow_8177.html |
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