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Metal-Organic Frameworks Derived Nanotube of Nickel–Cobalt Bimetal Phosphides as Highly Efficient Electrocatalysts for Overall Water Splitting
The design of highly efficient, stable, and noble-metal-free bifunctional electrocatalysts for overall water splitting is critical but challenging. Herein, a facile and controllable synthesis strategy for nickel–cobalt bimetal phosphide nanotubes as highly efficient electrocatalysts for overall water splitting via low-temperature phosphorization from a bimetallic metal-organic frame...
http://www.polymer.cnt//ss/zhaoxuebo/publicationsshow_12424.html
 
High Oxygen Reduction Activity on a Metal-Organic Framework derived Carbon Combined with High Degree of Graphitization and Pyridinic-N Dopants
N-doped porous carbons have been considered as one of the most promising earth-abundant catalysts for the oxygen reduction reaction (ORR) owing to their high activity and excellent stability. Among various types of N-containing groups, pyridinic-N has been identified as the most effective catalytic sites for the ORR, as demonstrated by a recent study. However, the fabrication of porous carbons w...
http://www.polymer.cnt//ss/zhaoxuebo/publicationsshow_12275.html
 
Metal-organic Frameworks Derived CoS2-Co/N-doped Porous Carbon with Extremely High Electrocatalytic Stability for the Oxygen Reduction Reaction
The electrocatalytic performances for the oxygen reduction reaction (ORR) highly depend on the structure and composition of catalysts. In this work, a novel non-precious metal catalyst (CoS2-Co/N-doped porous carbon) has been fabricated by the carbonization of metal-organic frameworks (MOFs) with a consequent sulfuration process. The resultant nanocomposite exhibits highly desirable structure feat...
http://www.polymer.cnt//ss/zhaoxuebo/publicationsshow_12274.html
 
[J.Phys.Chem.C ]Highly Efficient Electromagnetic Wave Absorbing Metal-Free and Carbon-Rich Ceramics Derived from Hyperbranched Polycarbosilazanes
Abstract: The highly efficient electromagnetic (EM) wave absorbing metal-free and carbon-rich ceramics derived from hyperbranched polycarbosilazanes were presented in this contribution. The novel metal-free hyperbranched polycarbosilazanes with pendant cyano groups (hb-PCSZ-cyano) were synthesized through aminolysis reaction and subsequent Michael addition reaction, i.e. cyanoethylation reaction...
http://www.polymer.cnt//ss/kongjie/publicationsshow_12267.html
 
Highly 2,3-Selective Polymerization of Phenylallene and Its Derivatives with Rare-Earth Metal Catalysts: From Amorphous to Crystalline Products
Rare-earth metal complexes (Flu-CH2-Py)Ln-(CH2SiMe3)2(THF)n (Ln=Sc(1), Lu(2), Tm(3), Y(4) andGd(5)), upon the activation of [Ph3C][B(C6F5)4] and AliBu3,were employed to catalyze the polymerization of allene derivatives under mild conditions. The Gd, Y, Tm, Lu metal based precursors exhibited distinguished 2,3-selectivity(>99.9%) for phenylallene (PA) polymerization, whereas the smallest Sc me...
http://www.polymer.cnt//ss/dongmeicui/publicationsshow_12264.html
 
Self-Powered Acceleration Sensor Based on Liquid Metal Triboelectric Nanogenerator for Vibration Monitoring
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http://www.polymer.cnt//ss/weiqingyang/publicationsshow_12133.html
 
[Angew. Chem. Int. Ed. 2017, 56, 7625] The Structural Fate of Individual Multicomponent Metal-Oxide Nanoparticles in Polymer Nanoreactors
http://onlinelibrary.wiley.com/doi/10.1002/anie.201703296/abstract
http://www.polymer.cnt//ss/xiezhuang/publicationsshow_12110.html
 
[Adv. Mater. 2013, 25, 3343] Matrix-Assisted Catalytic Printing for the Fabrication of Multi-Scale, Flexible, Foldable, and Stretchable Metal Conductors
http://onlinelibrary.wiley.com/doi/10.1002/adma.201301184/abstract
http://www.polymer.cnt//ss/xiezhuang/publicationsshow_12078.html
 
Rare earth metal bis(alkyl) complexes bearing amino phosphine ligands: Synthesis and catalytic activity toward ethylene polymerization
Reactions of neutral amino phosphine compounds HL1-3 with rare earth metal tris(alkyl)s, Ln(CH2SiMe3)(3)(THF)(2), afforded a new family of organolanthanide complexes, the molecular structures of which are strongly dependent on the ligand framework. Alkane elimination reactions between 2-(CH3NH)-C6H4P(Ph)(2) (HL1) and Lu(CH2SiMe3)(3)(THF)(2) at room temperature for 3 h ge...
http://www.polymer.cnt//ss/dongmeicui/publicationsshow_12020.html
 
Rare earth metal alkyl complexes bearing N,O,P multidentate ligands: Synthesis, characterization and catalysis on the ring-opening polymerization of L-lactide
Alkane elimination reactions of rare earth metal tris(alkyl)s, Ln(CH2SiMe3)3(THF)2 (Ln = Y, Lu) with the multidentate ligands HL1-4, afforded a series of new rare earth metal complexes. Yttrium, complex I supported by flexible amino-intino phenoxide ligand HL1 was isolated as homoleptic product. In the reaction of rigid phosphino-imino phenoxide ligand HL ...
http://www.polymer.cnt//ss/dongmeicui/publicationsshow_12019.html
 
 
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