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6. Green Photocatalysis with Oxygen Sensitive BODIPYs
作者:zhigang xie
关键字:photocatalysis
论文来源:期刊
发表时间:2014年
Four oxygen-sensitive meso-phenyl group with
p-azo   function   Boron-dipyrromethene   (BODIPY)   dyes
were  synthesized,  and  their  structures  and  photophysical
properties were studied by
1
H NMR, cyclic voltammetry
and emission spectroscopy. Oxygen-sensing properties of
BODIPYs  are  relevant  to  their  catalytic  activity  under
visible light. They were used to photocatalize oxidation of
thioanisole. These metal-free visible-light catalytic agents
could  complete  100 %  conversation  from  thioanisole  to
methylphenyl sulfoxide.