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Current Location :> Home > Publications > Text
Applied Surface Science 2012, 258, 2655
writer:Xiujuan Huang, Yan Xiao*, Wei Zhang, Meidong Lang*
keywords:silver nanoparticles; star-shaped copolymers; poly(ε-caprolactone); coordination reduction; nanoreactors; catalytic activity.
source:期刊
Issue time:2012年
Silver nanoparticles (Ag NPs) were prepared via in-situ reduction of silver nitrate (AgNO3) using polymeric micelles as nanoreactors without any additional reductant. The micelles were constructed from the amphiphilic star-shaped copolymer composed of poly(ε-caprolactone) (PCL) segment, 2-(Dimethylamino)ethyl methacrylate (DMAEMA or DMA) units and oligo(ethylene glycol)monomethyl ether methacrylate (OEGMA or OEG) units. The Ag NPs stabilized by those star-shaped copolymers were characterized using UV-vis spectrum, DLS, TEM and FT-IR. It confirmed that PDMAEMA exhibited the reducing property unless pH was above 7. The Ag NPs were sphere-like with a diameter of 10-20 nm, which was independent of the architecture of the copolymer and AgNO3 concentration. Furthermore, the catalytic activity of these Ag NPs was investigated by monitoring the reduction of p-nitrophenol (4-NP) by NaBH4. The result showed that the Ag NPs formed by coordination reduction can be effectively applied in catalytic reaction.