作者：Siyuan Liu, Jiajia Yu, Yuchen Chao, Defeng Wu*
关键字：chitin nanocrystals (ChNCs); eutectogel; sensing.
论文来源：期刊
具体来源：International Journal of Biological Macromolecules
发表时间：2026年

International Journal of Biological Macromolecules, 2026,

Using polysaccharide nanocrystals to regulate networks is a promising way to open up more functions and application scenarios for the eutectogels. A chitin nanocrystals (ChNCs)-containing eutectogel was fabricated herein via a ‘two-step’ method for the study. Using carboxymethyl chitosan/poly(vinyl alcohol) as the matrices, the hydrogel networks were constructed via the freeze-thawing treatment and boronic esterification, and then underwent solvent exchange with glycerol/choline chloride. The as-obtained eutectogel has a well-defined structure, in which ChNCs act as a ‘reinforcing bar’ and boronic ester (B-O-C) bonding as a ‘bridge’, collaboratively strengthen the eutectogel networks. The strength (1.75 MPa) and modulus (0.65 MPa) are improved remarkably, enhancing by 38% and 55% than those of the eutectogels free of ChNCs and B-O-C bonds. Moreover, the clustering-triggered emission (CTE) capability of eutectogels is evidently enhanced because ChNCs can rigidify the eutectogel networks with the aid of B-O-C bonding. Therefore, the developed fluorescent eutectogel exhibits a variety of potential applications: encrypting specific information by tuning the heterogeneity of eutectogel patterns, monitoring fruit freshness by capturing the volatile substances released during spoilage, and perceiving strain/thermal alterations as a soft substrate. This work paves a feasible approach of using polysaccharide nanocrystals to construct the eutectogel-based multi-tasking platform.

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https://www.sciencedirect.com/science/article/abs/pii/S0141813026045691