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Synergetic photo-epoxidation of propylene with molecular oxygen over bimetallic Au-Ag/TS-1 photocatalysts
作者:Li, NX (Li, Naixu)[ 1 ] ; Yang, B (Yang, Bin)[ 1 ] ; Liu, M (Liu, Ming)[ 1 ] ; Chen, Y (Chen, Yong)[
关键字:Gold; Silver; Titanium silicalite-1; Photocatalysis; Propene epoxidation; Synergetic effect
论文来源:期刊
具体来源:CHINESE JOURNAL OF CATALYSIS
发表时间:2017年

Au-Ag bimetallic nanoparticle-supported microporous titanium silicalite-1 catalysts were prepared via a hydrothermal-immersion method, and their structures were examined. These materials serve as efficient catalysts for the photosynthesis of propylene oxide via the epoxidation of propene. The Au/Ag mass ratio and reaction temperature were demonstrated to have significant effects on the catalytic activity and selectivity of propylene oxide. The optimal formation rate (68.3 mu mol/g.h) and selectivity (52.3%) toward propylene oxide were achieved with an Au:Ag mass ratio of 4:1. Notably, the strong synergistic effect between Au and Ag resulted in superior photocatalysis of the bimetallic systems compared with those of the individual systems. A probable reaction mechanism was proposed based on the theoretical and experimental results. (C) 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.