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Preparation of Chitosan/Poly (vinyl alcohol) Blends Nanofibrous Matrix  
Preparation of Chitosan/Poly (vinyl alcohol) Blends Nanofibrous Matrix
资料类型: PDF文件
关键词: Preparation  of  Chitosan/Poly  (vinyl  alcohol)  Blends  Nanofibrous  
Matrix  
资料大小: 420K
所属学科: 分子表征
来源: 2005年新型纤维与聚合物材料国际学术会议(10.19-10.21,上海)
简介:
Anelectrospinningmethodwasusedtofabricatechitosan(CS)/poly(vinylalcohol)(PVA)blendsnanofibrousmatrix.Theinfluencesofvariousprocessingparametersondiameterandmorphologyoftheelectrospunnanofiberswereinvestigatedbyscanningelectronmicroscopy(SEM)technique.Thepropertiesofsolutionwithdifferentweightratio,suchasconductivityandviscosity,weremeasured.Theresultsindicatedthattheaveragediameterofthefibersincreasedwithincreasingoftheconcentrationandthemorphologychangedgraduallyfrommorebeadsstructuretotheuniformfiber-structurewithincreasingoftheconcentrationofsolutionfrom3wt%to9.5wt%.ThediameteroftheelectrospunfibersdecreasedwiththeincreasingofCScontentsintheblendfrom10%to30%.However,attheblendcompositionswithabove30%CS,theblendnanofiberswerenotabletoelectrospunintothefibrousstructure.HighervoltageandlargerTCD(tip-to-collectordistance)favoredtheformationofsmallerdiameteroftheelectrospunfibers.TheFouriertransforminfrared(FT-IR)analysisdemonstratedthattherewerestronginteractionsbetweenCSandPVAmolecularresultedfromintermolecularhydrogenbonds.
作者: Yongtang Jia Xiaohua Gu Fengchun Dong Xinyuan Shen
上传时间: 2007-08-07 15:32:00
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