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[ACS Macro Lett.] Lewis Pair-Mediated Surface-Initiated Polymerization  
[ACS Macro Lett.] Lewis Pair-Mediated Surface-Initiated Polymerization
资料类型: PDF文件
关键词: Lewis  Pairs  Surface-Initiated  Polymerization  Polymer  Brushes  
资料大小: 1379k
所属学科: 高分子化学
来源: 来源网络
简介:
We present the first example of surface-initiated polymerization mediated by Lewis pairs for the synthesis of polymer brushes on planar substrates. The method enables the rapid grafting polymerization from the self-assembled monolayer or surface-attached macroinitiators, furnishing linear polymer brushes and bottle-brush brushes. Both homopolyester and block copolyester brushes can be synthesized via this versatile approach. This work not only opens up new opportunities for the application of Lewis pair-mediated polymerization but also enriches the surface-initiated polymerization on different surfaces.
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