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Nonisothermal crystallization kinetics of bio-based semi-aromatic polyamides  
Nonisothermal crystallization kinetics of bio-based semi-aromatic polyamides
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关键词: poly(decamethylene  terephthalamide)  Nonisothermal  crystallization  kinetics  Biobased  Semi-aromatic  
polyamides  
资料大小: 871k
所属学科: 高分子化学
来源: 来源网络
简介:
Semi-aromatic copolyamides PA10T10I and PA10T10F based on bio-based poly(decamethylene terephthalamide) (PA10T) were synthesized by a two-step polycondensation technique. The nonisothermal crystallization of these semi-aromatic polyamides was investigated by differential scanning calorimetry. Avrami theory modified by Jeziorny and Mo equation was used to describe the nonisothermal crystallization kinetics of these semi-aromatic polyamides, respectively. The crystallization activation energies were obtained by Kissinger method. The crystallization temperature, crystallization rate and activation energy were explained by regularity and flexibility of chain.
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上传时间: 2019-03-29 15:13:53
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