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实验验证广义二维相关光谱中的“序列顺序”规则 |
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资料类型: |
Word文件
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关键词: |
广义二维相关光谱 “序列顺序”规则 |
资料大小: |
254K |
所属学科: |
分子表征 |
来源: |
2008年第六届全国高聚物分子与结构表征学术讨论会(9.27-9.30,重庆) |
简介: |
Followingourtheoreticalanalysisonthe“sequentialorder”rulesingeneralizedtwo-dimensional(2D)correlationspectroscopy(Huang,H.Anal.Chem.2007,79,8281-8292),anexperimentalstudywasconductedtotestthe“sequentialorder”rules.Thefindingsrevealedthatdifferentintegratedoroverallsequentialorderscouldbeobtainedbyselectionofdifferentsamplingintervalswiththesamelocalsequentialorder,orchoosingsamedatasetbutwithdifferentcontour(calculation)levels.Theseintegratedoroverallsequentialordersobtainedfromgeneralized2Dcorrelationspectroscopymayormaynotbeidenticaltothelocalsequentialorder,whichreflectstherealsequentialorderbetweentwoeventsingeneralizedsituations.Inaddition,2Dcorrelationanalysisalwaysgeneratestheintegratedoroverallsequentialorderoftwoeventsevenwithnolocalsequentialorder.Cautionmustbeemployedwiththeapplicationofgeneralized2Dcorrelationspectroscopywhilederivingsequentialordersforanytwoevents. |
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作者: |
黄鹤,武培怡,Christian Vogel,Heinz W. Siesler
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上传时间: |
2009-03-06 16:15:43 |
下载次数: |
1 |
消耗积分: |
2
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